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Cited by 295

The DOI matches its Crossref record; 11 of the 11 references it cites were found in a registry or an index.

Production of Hollow Microspheres from Nanostructured Composite Particles

Caruso, Frank, Caruso, Rachel A., Möhwald, Helmuth·1999·Chemistry of Materials

Abstract

Uniform inorganic and hybrid inorganic−organic hollow microspheres have been produced by coating colloidal core templates with alternating layers of oppositely charged nanoparticles and polymer, and thereafter removing the core either by heating or chemical treatment. The multilayers were constructed by consecutively depositing the nanoparticles and polymer onto the colloidal templates, utilizing the electrostatic attraction between the particles and polymer for layer build-up. Hollow silica spheres were obtained by calcining polymer latex spheres coated with multilayers of silica nanoparticles (SiO 2 ) bridged by polymer [poly(diallyldimethylammonium chloride) (PDADMAC)]. Exposure of SiO 2 /PDADMAC multilayer-coated polymer latex colloids to acidic solutions, dimethyl sulfoxide, or tetrahydrofuran yielded hollow composite silica−polymer spheres. The fabricated hollow spheres have been characterized using scanning and transmission electron microscopy. The approach employed is well suited to generating hollow spheres of controlled diameter, wall thickness, and composition.

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Crossref · 10.1021/cm991083p

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Metadata

Authors
Caruso, F., Caruso, R. A., & Möhwald, H.
Venue
Chemistry of Materials
Published
1999-10-13
Volume
11
Issue
11
Pages
3309-3314
ISSN
  • 0897-4756 (ISSN-L)
  • 1520-5002
OpenAlex
W2016340107
Cited by
295
References
11
FWCI
6.86
Type
journal article
Language
en
Open access
closed

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

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