The DOI matches its Crossref record; 18 of the 18 references it cites were found in a registry or an index.
Layered Hydroxide Metal Acetates (Metal = Zinc, Cobalt, and Nickel): Elaboration via Hydrolysis in Polyol Medium and Comparative Study
Abstract
Layered hydroxide metal acetates (metal = zinc, cobalt, and nickel) have been prepared by a new route belonging to the chimie douce method. This novel method involves the hydrolysis, in polyol medium, of in situ-formed complexes supposed to be alkoxyacetates. These layered hydroxide metal acetates present poorly ordered character, and their X-ray patterns have features typical of lamellar compounds with turbostratic disorder. Their chemical formula was established to be M(OH) 2 - x (CH 3 COO) x · n H 2 O with ( x, n ) = (0.42, 0.31), (0.38, 0.53), and (0.40, 0.63) for Zn, Co, and Ni, respectively. The layered hydroxide nickel acetate has a classical brucite structure with a random substitution of some hydroxyl groups by acetate groups. The layered hydroxide zinc and cobalt acetates are isomorphous with the hydrozincite structure, in which cations are located in both octahedral and tetrahedral sites. The acetate anion behaves as a unidentate ligand in LHS−Ni and LHS−Co, where LHS indicates layered hydroxide salt, and is intercalated as a free anion in the zinc compound. The dehydration is a reversible topotactic process for LHS−Ni and Co, whereas it is a destructive process in the case of LHS−Zn.
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Cites
Nakamoto, K. (2008) · Wiley eBooks · doi:10.1002/9780470405888 · Cited by 8,429
Hydrotalcite-type anionic clays: Preparation, properties and applications.
Cavani, F., Trifirò, F., & Vaccari, A. (1991) · Catalysis Today · doi:10.1016/0920-5861(91)80068-k · Cited by 5,980
Inorganic electronic spectroscopy
R, G. (1985) · Journal of Molecular Structure · doi:10.1016/0022-2860(85)80208-8 · Cited by 5,884
FIEVET, F., LAGIER, J., BLIN, B., BEAUDOIN, B., & FIGLARZ, M. (1989) · Solid State Ionics · doi:10.1016/0167-2738(89)90222-1 · Cited by 840
Preparing Monodisperse Metal Powders in Micrometer and Submicrometer Sizes by the Polyol Process
Fievet, F., Lagier, J. P., & Figlarz, M. (1989) · MRS Bulletin · doi:10.1557/s0883769400060930 · Cited by 585
Monodisperse Ferromagnetic Particles for Microwave Applications
Toneguzzo, P., Viau, G., Acher, O., Fiévet-Vincent, F., & Fiévet, F. (1998) · Advanced Materials · doi:10.1002/(sici)1521-4095(199809)10:13<1032::aid-adma1032>3.0.co;2-m · Cited by 348
Self-citationLabajos, F. M., Rives, V., & Ulibarri, M. A. (1992) · Journal of Materials Science · doi:10.1007/bf00542916 · Cited by 324
The crystal structure of zinc hydroxide nitrate, Zn5(OH)8(NO3)2.2H2O
Stählin, W., & Oswald, H. R. (1970) · Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry · doi:10.1107/s0567740870003230 · Cited by 253
Submicrometer zinc oxide particles: Elaboration in polyol medium and morphological characteristics
Jézéquel, D., Guenot, J., Jouini, N., & Fiévet, F. (1995) · Journal of Materials Research · doi:10.1557/jmr.1995.0077 · Cited by 237
Self-citationThe crystal structure of hydrozincite, Zn5(OH)6(CO3)2
Ghose, S. (1964) · Acta Crystallographica · doi:10.1107/s0365110x64002651 · Cited by 202
Kooli, F., Chisem, I. C., Vučelić, M., & Jones, W. (1996) · Chemistry of Materials · doi:10.1021/cm960070y · Cited by 171
On the Existence of Hydrotalcite-Like Phases in the Absence of Trivalent Cations
Kamath, P. V., Annal Therese, G. H., & Gopalakrishnan, J. (1997) · Journal of Solid State Chemistry · doi:10.1006/jssc.1996.7144 · Cited by 160
Baddour‐Hadjean, R., Pereira‐Ramos, J., Messina, R., & Périchon, J. (1991) · Journal of Electroanalytical Chemistry · doi:10.1016/0022-0728(91)85430-w · Cited by 125
Alcohol as ligands. III. Complexes of Ethylene glycol with some divalent metal halides
Knetsch, D., & Groeneveld, W. L. (1973) · Inorganica Chimica Acta · doi:10.1016/s0020-1693(00)94784-4 · Cited by 114
Chemical Synthesis of Fine Powders
Livage, J., Henry, M., Jolivet, J., & Sánchez, C. (1990) · MRS Bulletin · doi:10.1557/s0883769400060693 · Cited by 67
The cobalt hydroxide electrode—II. Electrochemical behaviour
Benson, P., Briggs, G. W. D., & Wynne-Jones, W. F. K. (1964) · Electrochimica Acta · doi:10.1016/0013-4686(64)80017-7 · Cited by 48
NISHIZAWA, H., Kishikawa, T., & Minami, H. (1999) · Journal of Solid State Chemistry · doi:10.1006/jssc.1999.8302 · Cited by 22
Cited by
Laurent, S., Forge, D., Port, M., Roch, A., Robic, C., Vander Elst, L., & Muller, R. N. (2008) · Chemical Reviews · doi:10.1021/cr068445e · Cited by 6,852
Ye, S., Shi, Z., Feng, J., Tong, Y., & Li, G. (2018) · Angewandte Chemie International Edition · doi:10.1002/anie.201712549 · Cited by 561
Tatarchuk, S. W., Choueiri, R. M., Medvedeva, X. V., Chen, L. D., & Klinkova, A. (2021) · Chemosphere · doi:10.1016/j.chemosphere.2021.130550 · Cited by 56
Metadata
- Authors
- Poul, L., Jouini, N., & Fiévet, F.
- Venue
- Chemistry of Materials
- Publisher
- American Chemical Society (ACS)
- Published
- 2000-09-23
- Volume
- 12
- Issue
- 10
- Pages
- 3123-3132
- ISSN
- 0897-4756 (ISSN-L)
- 1520-5002
- OpenAlex
- W1976535522
- Cited by
- 481
- References
- 18
- FWCI
- 3.40
- Type
- journal article
- Language
- en
- Open access
- closed
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