Cationic Organometallic Complexes of Scandium, Yttrium, and the Lanthanoids

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Cocatalysts for Metal-Catalyzed Olefin Polymerization: Activators, Activation Processes, and Structure−Activity Relationships

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Carbon‐Hydrogen‐Transition Metal Bonds

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Endohedral metallofullerenes

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The search for larger and more weakly coordinating anions

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Chemistry of Cationic Dicyclopentadienyl Group 4 Metal-Alky I Complexes

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Ion Pairing in Transition-Metal Organometallic Chemistry

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Living Polymerization of α-Olefins by Chelating Diamide Complexes of Titanium

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Recent developments in organolanthanide polymerization catalysts

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Non-cyclopentadienyl ancillaries in organogroup 3 metal chemistry: a fine balance in ligand design

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Disodium tetracarbonylferrate, a transition metal analog of a Grignard reagent

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Scandium Half-Metallocene-Catalyzed Syndiospecific Styrene Polymerization and Styrene−Ethylene Copolymerization: Unprecedented Incorporation of Syndiotactic Styrene−Styrene Sequences in Styrene−Ethylene Copolymers

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Chemistry of Tris(pentamethylcyclopentadienyl) f-Element Complexes, (C5Me5)3M

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Group 3 metal catalysts for ethylene and α-olefin polymerization

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Stable silylmethyl and neopentyl complexes of scandium(III) and yttrium(III)

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One Ligand Fits All: Cationic Mono(amidinate) Alkyl Catalysts over the Full Size Range of the Group 3 and Lanthanide Metals

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Organometallic Chemistry of the Lanthanides

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Cationic Scandium Methyl Complexes Supported by a β-Diketiminato (“Nacnac”) Ligand Framework

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Synthesis of monomeric permethylyttrocene derivatives. The crystal structures of Cp2*YN(SiMe3)2 and Cp2*YCH(SiMe3)2

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Cationic Alkyl Complexes of the Rare‐Earth Metals: Synthesis, Structure, and Reactivity

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Reactivity of trimethylaluminum with (C5Me5)2Sm(THF)2: synthesis, structure, and reactivity of the samarium methyl complexes (C5Me5)2Sm[(.mu.-Me)AlMe2(.mu.-Me)]2Sm(C5Me5)2 and (C5Me5)2SmMe(THF)

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Unsolvated Lanthanide Metallocene Cations [(C5Me5)2Ln][BPh4]: Multiple Syntheses, Structural Characterization, and Reactivity Including the Formation of (C5Me5)3Nd1

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Yttrium alkyl complexes with a sterically demanding benzamidinate ligand: synthesis, structure and catalytic ethene polymerisationElectronic supplementary information (ESI) available: experimental details. See http://www.rsc.org/suppdata/cc/b2/b208502j/

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Synthesis of Dialkylscandium Complexes Supported by β-Diketiminato Ligands and Activation with Tris(pentafluorophenyl)borane

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A New Chelating Anilido-Imine Donor Related to β-Diketiminato Ligands for Stabilization of Organoyttrium Cations

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Rare earth metal complexes that contain linked amido-cyclopentadienyl ligands: ansa-metallocene mimics and “constrained geometry” catalysts

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Conjugated Diene Polymerization

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Lanthanide Borohydrides as Precursors to Organometallic Compounds. Mono(cyclooctatetraenyl) Neodymium Complexes

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Synthesis and Comparative η1-Alkyl and Sterically Induced Reduction Reactivity of (C5Me5)3Ln Complexes of La, Ce, Pr, Nd, and Sm

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Highly electron deficient group 3 organometallic complexes based on the 1,4,7-trimethyl-1,4,7-triazacyclononane ligand system

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Stereospecific Polymerization of 1,3-Butadiene with Samarocene-Based Catalysts

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Neutral and anionic silylmethyl complexes of the Group 3a and lanthanoid metals; the X-ray crystal and molecular structure of [Li(thf)4][Yb{CH(SiMe3)2}3Cl](thf = tetrahydrofuran)

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Ultimately Specific 1,4‐cis Polymerization of 1,3‐Butadiene with a Novel Gadolinium Catalyst

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Nuclear magnetic resonance studies of organometallic exchange processes

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Neutral and cationic yttrium alkyl complexes with linked 1,4,7-triazacyclononane-amide monoanionic ancillary ligands: synthesis and catalytic ethene polymerisation

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Synthetic Utility of [(C5Me5)2Ln][(μ-Ph)2BPh2] in Accessing [(C5Me5)2LnR]x Unsolvated Alkyl Lanthanide Metallocenes, Complexes with High C−H Activation Reactivity

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Chemistry of (octaethylporphyrinato)lutetium and -yttrium complexes: synthesis and reactivity of (OEP)MX derivatives and the selective activation of O2 by (OEP)Y(.mu.-Me)2AlMe2

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Metallorganische verbindungen der lanthaniden

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Neutral and Cationic Alkyl and Alkynyl Complexes of Lanthanum: Synthesis, Stability, and Cis-Selective Linear Alkyne Dimerization

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First Chemical Transformations of Lanthanide Borohydride Compounds: Synthesis and Crystal Structures of [(η-C8H8)Nd(BH4)(THF)]2 and [(η-C8H8)Nd(THF)4][BPh4]

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Random- and Block-Copolymerization of 1,3-Butadiene with Styrene Based on the Stereospecific Living System: (C5Me5)2Sm(μ-Me)2AlMe2/Al(i-Bu)3/[Ph3C][B(C6F5)4]

Kaita, S., Hou, Z., & Wakatsuki, Y. (2001) · Macromolecules · doi:10.1021/ma001609n · Cited by 99

Komplexkatalyse

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Tethered Olefin Studies of Alkene versus Tetraphenylborate Coordination and Lanthanide Olefin Interactions in Metallocenes

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Highly efficient ethylene polymerisation by scandium alkyls supported by neutral fac-κ 3 coordinated N 3 donor ligands

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Naked (C5Me5)2M Cations (M = Sc, Ti, and V) and Their Fluoroarene Complexes

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Cationic lanthanide alkyl complexes. Evidence for an unprecedented tetraphenylborate coordination mode in La(C5Me5){CH(SiMe3)2}BPh4

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The first structurally characterized cationic lanthanide–alkyl complexesElectronic supplementary information (ESI) available: experimental and spectroscopic details. See http://www.rsc.org/suppdata/cc/b2/b201613n/

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Alkyl Complexes of Rare-Earth Metals That Contain a Furyl-Functionalized Cyclopentadienyl Ligand: Alkyl Cation Formation and Unexpected Ring-Opening Reaction of the Furyl Group

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The Elusive (C 5 Me 4 H) 3 Lu: Its Synthesis and LnZ 3 /K/N 2 Reactivity

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Synthesis, X-ray Crystal Structure, and Reactivity of Y(MAC)(CH2SiMe3)2 (MAC = Deprotonated aza-18-crown-6)

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Agostische Wechselwirkungen in d0‐Alkylmetallkomplexen

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Unusual alkyl group activation and cationic complex formation from a novel lutetium dialkyl complex supported by a tridentate monoanionic ligandElectronic supplementary information (ESI) available: details of the synthesis of 2 and 3 and the hydrolysis of 3. See http://www.rsc.org/suppdata/cc/b3/b306889g/

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Synthesis and Structure of Tris(alkyl- and silyl-tetramethylcyclopentadienyl) Complexes of Lanthanum

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Neutral and cationic trimethylsilylmethyl complexes of the rare earth metals supported by a crown ether: synthesis and structural characterization

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Homogeneous Ethylene‐Polymerization Catalysts Based on Alkyl Cations of the Rare‐Earth Metals: Are Dicationic Mono(alkyl) Complexes the Active Species?

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The First Crystallographically Characterized (Perfluoroaryl)lanthanoid(II) Complex, Eu(C6F5)2(OC4H8)5

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Synthesis of cationic cerium compounds [Cp*2Ce(L)2][BPh4] (L = tetrahydrofuran or tetrahydrothiophene) and the crystal structure of the tetrahydrothiophene derivative

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Displacement of a cyclopentadienyl ligand by a crown ether from a lanthanocene(ii) [LnCp′′2]; crystal structures of the first cationic lanthanoid(ii) complexes, [SmCp′′([18]-crown-6)][SmCp′′3]·0.5C6H6 and [YbCp′′([18]-crown-6)][Cp′′]·3C6H6 [Cp′′ = η5-C5H3(SiMe3)2-1,3]

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Neodymium and uranium borohydride complexes, precursors to cationic derivatives: comparison of 4f and 5f element complexes

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A Comparison of Analogous 4f‐ and 5f‐Element Compounds: Syntheses and X‐ray Crystal Structures of the Mixed Sandwich Complexes [M(η‐C8H8)(L){OP(NMe2)3}] (M = Nd or U; L = η‐C5Me5 or η‐C4Me4P)

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Synthesis and Structures of the First Cationic Perfluoroaryllanthanoid( II ) Complexes

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Theoretical Study of Coordination and Insertion of Butadiene to Bis(pentamethylcyclopentadienyl)samarium Hydride

Kaita, S., Koga, N., Hou, Z., Doi, Y., & Wakatsuki, Y. (2003) · Organometallics · doi:10.1021/om030162e · Cited by 29

Synthesis and molecular structure of [(t-C4H9C5H4) 2Yb(THF)2][BPh4] · THF and its catalytic activity for the polymerization of styrene

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Cationic monocyclooctatetraenyl-lanthanoid complexes derived from metallic lanthanoid: crystal structures of [Sm(η8−C8H8)(hmpa)3]I and [Sm(η8−C8H8)(hmpa)3][Sm(η8−C8H8)2] (HMPA = hexamethylphosphoric triamide)

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3d Transition Metals for C–H Activation

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