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Lanthanides and Actinides in Ionic Liquids
Abstract
An overview of the properties and applications of f-elements in room temperature ionic liquids with lanthanides and actinides has been presented. Theoretical and experimental studies of the solvation of f-element in ionic liquids are considered. Also, the spectroscopic properties of lanthanides and actinide ions are discussed with emphasis on the luminescence properties. Because of the ionic liquids' ionic nature and redox stability, it is used as solvents for lanthanide ions in unusual oxidation states. Also included in the review is the behavior of ionic liquids in solvent extraction of metal ions compared with that of molecular solvents and its application for the processing of spent nuclear fuel rods. Ionic liquids advantage is that the processing can be carried out at much lower temperature than in inorganic molten salts thus, energy cost will be reduced and safety will also be increased.
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Abbott, A. P., Capper, G., Davies, D. L., Rasheed, R. K., & Tambyrajah, V. (2003) · Chemical Communications · doi:10.1039/b210714g · Cited by 5,738
Applications of ionic liquids in the chemical industry
Plechkova, N. V., & Seddon, K. R. (2008) · Chem. Soc. Rev. · doi:10.1039/b006677j · Cited by 5,686
Influence of chloride, water, and organic solvents on the physical properties of ionic liquids
Seddon, K. R., Stark, A., & Torres, M.-J. (2000) · Pure and Applied Chemistry · doi:10.1351/pac200072122275 · Cited by 2,293
Metal Chlorides in Ionic Liquid Solvents Convert Sugars to 5-Hydroxymethylfurfural
Zhao, H., Holladay, J. E., Brown, H., & Zhang, Z. C. (2007) · Science · doi:10.1126/science.1141199 · Cited by 1,997
Dissolution of cellulose with ionic liquids and its application: a mini-review
Zhu, S., Wu, Y., Chen, Q., Yu, Z., Wang, C., Jin, S., Ding, Y., & Wu, G. (2006) · Green Chemistry · doi:10.1039/b601395c · Cited by 1,260
H. Davis, J. (2004) · Chemistry Letters · doi:10.1246/cl.2004.1072 · Cited by 1,053
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Recycling of rare earths: a critical review
Binnemans, K., Jones, P. T., Blanpain, B., Van Gerven, T., Yang, Y., Walton, A., & Buchert, M. (2013) · Journal of Cleaner Production · doi:10.1016/j.jclepro.2012.12.037 · Cited by 2,382
Self-citationIonic liquids and catalysis: Recent progress from knowledge to applications
Olivier-Bourbigou, H., Magna, L., & Morvan, D. (2010) · Applied Catalysis A: General · doi:10.1016/j.apcata.2009.10.008 · Cited by 1,639
Green Routes for Synthesis of Zeolites
Meng, X., & Xiao, F.-S. (2014) · Chemical Reviews · doi:10.1021/cr4001513 · Cited by 635
Recent Developments in Synthesis and Structural Chemistry of Nonaqueous Actinide Complexes
Jones, M. B., & Gaunt, A. J. (2013) · Chemical Reviews · doi:10.1021/cr300198m · Cited by 323
Mori, T., Takao, K., Sasaki, K., Suzuki, T., Arai, T., & Ikeda, Y. (2015) · Separation and Purification Technology · doi:10.1016/j.seppur.2015.01.045 · Cited by 45
Metadata
- Authors
- Binnemans, K.
- Venue
- Chemical Reviews
- Publisher
- American Chemical Society (ACS)
- Published
- 2007-05-23
- Volume
- 107
- Issue
- 6
- Pages
- 2592-2614
- ISSN
- 0009-2665 (ISSN-L)
- 1520-6890
- OpenAlex
- W2008126194
- Cited by
- 672
- References
- 6
- FWCI
- 1.56
- Type
- journal article
- Language
- en
- Open access
- closed
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