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Polyanionic (Phosphates, Silicates, Sulfates) Frameworks as Electrode Materials for Rechargeable Li (or Na) Batteries
Abstract
For more than 20 years, most of the technological achievements for the realization of positive electrodes for practical rechargeable Li battery systems have been devoted to transition metal oxides such as LixMO2 (M = Co, Ni, Mn), LixMn2O4, LixV2O5, or LixV3O8. The first two classes of materials built on close-packed oxygen stacking adopt bidimensional and tridimensional crystal structures, respectively (Figure 1), from which lithium ions may be easily intercalated or extracted in a reversible manner. These oxides are reasonably good ionic and electronic conductors, and lithium insertion/extraction proceeds while operating on the M4+/M3+ redox couple, located between 4 and 5 V versus Li+/Li...
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Cited by
Myung, S.-T., Maglia, F., Park, K.-J., Yoon, C. S., Lamp, P., Kim, S.-J., & Sun, Y.-K. (2017) · ACS Energy Letters · doi:10.1021/acsenergylett.6b00594 · Cited by 1,382
Towards polyvalent ion batteries: A zinc-ion battery based on NASICON structured Na3V2(PO4)3
Li, G., Yang, Z., Jiang, Y., Jin, C., Huang, W., Ding, X., & Huang, Y. (2016) · Nano Energy · doi:10.1016/j.nanoen.2016.04.051 · Cited by 734
Vanadium‐Based Nanomaterials: A Promising Family for Emerging Metal‐Ion Batteries
Xu, X., Xiong, F., Meng, J., Wang, X., Niu, C., An, Q., & Mai, L. (2020) · Advanced Functional Materials · doi:10.1002/adfm.201904398 · Cited by 482
An Overview and Future Perspectives of Rechargeable Zinc Batteries
Shi, Y., Chen, Y., Shi, L., Wang, K., Wang, B., Li, L., Ma, Y., Li, Y., Sun, Z., Ali, W., et al. (2020) · Small · doi:10.1002/smll.202000730 · Cited by 389
Sun, Y., Guo, S., & Zhou, H. (2019) · Energy & Environmental Science · doi:10.1039/c8ee01006d · Cited by 322
Metadata
- Authors
- Masquelier, C., & Croguennec, L.
- Venue
- Chemical Reviews
- Publisher
- American Chemical Society (ACS)
- Published
- 2013-06-06
- Volume
- 113
- Issue
- 8
- Pages
- 6552-6591
- ISSN
- 0009-2665 (ISSN-L)
- 1520-6890
- OpenAlex
- W2331109089
- Cited by
- 1,210
- References
- 0
- FWCI
- 6.90
- Type
- journal article
- Language
- en
- Open access
- closed
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- Masquelier, C., & Croguennec, L. (2013). Polyanionic (Phosphates, Silicates, Sulfates) Frameworks as Electrode Materials for Rechargeable Li (or Na) Batteries. Chemical Reviews. https://doi.org/10.1021/cr3001862
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