The DOI matches its Crossref record; 21 of the 21 references it cites were found in a registry or an index.
Group 13 Compounds Incorporating Salen Ligands
Abstract
In a previous review it was predicted that "the reactivity of five-coordinate complexes would certainly be different than that of the four-coordinate derivatives". Structurally and spectroscopically, there is very little difference in the higher-coordinate compounds when compared to the four-coordinate derivatives. However, the prediction was remarkably accurate, if not a bit understated, for the reactivity of these compounds. There appears to be a tremendous potential in catalysis and synthesis for the five-coordinate derivatives, far more possibilities than exist for the lower-coordinate derivatives. Furthermore, the higher-coordinate derivatives are rarely air or moisture sensitive and, thus, may be handled under a wider range of conditions. Although reactions such as oxirane and lactide polymerizations are fairly well-known now with five- and six-coordinate aluminum compounds, the potential of these compounds has only begun to be developed. It is easy to imagine that these types of compounds will see wider use than the related transition-metal compounds.
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Cites
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Comprehensive Coordination Chemistry
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Metalloporphyrins as Initiators for Living and Immortal Polymerizations
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Lewis acids and selectivity in organic synthesis
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Self-citationBenn, R., Rufińska, A., Lehmkuhl, H., et al. (1983) · Angewandte Chemie International Edition in English · doi:10.1002/anie.198307791 · Cited by 155
Cationic Aluminum Compounds with Potential Relevance to Lewis Acid Catalysis
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Self-citationA New Class of Aluminum Cations Based upon Tetradentate (N 2 O 2 ) Chelating Ligands
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Cited by
Ovitt, T. M., & Coates, G. W. (2002) · Journal of the American Chemical Society · doi:10.1021/ja012052+ · Cited by 713
Reactive p-block cations stabilized by weakly coordinating anions
Engesser, T. A., Lichtenthaler, M. R., Schleep, M., & Krossing, I. (2016) · Chemical Society Reviews · doi:10.1039/c5cs00672d · Cited by 326
Material Applications for Salen Frameworks
Wezenberg, S. J., & Kleij, A. W. (2008) · Angewandte Chemie International Edition · doi:10.1002/anie.200702468 · Cited by 289
Gallium and indium complexes for ring-opening polymerization of cyclic ethers, esters and carbonates
Dagorne, S., Normand, M., Kirillov, E., & Carpentier, J.-F. (2013) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2013.02.012 · Cited by 215
Aluminum alkyl complexes: synthesis, structure, and application in ROP of cyclic esters
Wei, Y., Wang, S., & Zhou, S. (2016) · Dalton Transactions · doi:10.1039/c5dt04240b · Cited by 122
Metadata
- Authors
- Atwood, D. A., & Harvey, M. J.
- Venue
- Chemical Reviews
- Publisher
- American Chemical Society (ACS)
- Published
- 2000-12-20
- Volume
- 101
- Issue
- 1
- Pages
- 37-52
- ISSN
- 0009-2665 (ISSN-L)
- 1520-6890
- OpenAlex
- W2949289551
- Cited by
- 422
- References
- 21
- FWCI
- 0.76
- Type
- journal article
- Language
- en
- Open access
- closed
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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