The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
“One-Pot” Synthesis of 5-(Hydroxymethyl)furfural from Carbohydrates using Tin-Beta Zeolite
Open accessAbstract
Conversion of carbohydrates to 5-(hydroxymethyl)furfural (HMF) may provide a step forward toward achieving a renewable biomass-based chemicals and fuels platform. Recently, we reported that a tin-containing, high-silica molecular sieve with the zeolite beta topology (Sn-Beta) can efficiently catalyze the isomerization of glucose to fructose in aqueous media at low pH. Herein, we describe the combination of Sn-Beta with acid catalysts in a one vessel, biphasic reactor system to synthesize HMF from carbohydrates such as glucose, cellobiose, and starch with high efficiency. HMF selectivities over 70% were obtained using this “one-pot” biphasic water/tetrahydrofuran (THF) reactor system. The key to successfully achieving the conversions/selectivities reported is that Sn-Beta is able to convert glucose to fructose at pH near 1 and in saturated aqueous salt solutions.
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Citations
Cites
Catalytic conversion of biomass to biofuels
Alonso, D. M., Bond, J. Q., & Dumesic, J. A. (2010) · Green Chemistry · doi:10.1039/c004654j · Cited by 2,333
Metal Chlorides in Ionic Liquid Solvents Convert Sugars to 5-Hydroxymethylfurfural
Zhao, H., Holladay, J. E., Brown, H., & Zhang, Z. C. (2007) · Science · doi:10.1126/science.1141199 · Cited by 1,997
Cited by
Hydroxymethylfurfural, A Versatile Platform Chemical Made from Renewable Resources
van Putten, R.-J., van der Waal, J. C., de Jong, E., Rasrendra, C. B., Heeres, H. J., & de Vries, J. G. (2013) · Chemical Reviews · doi:10.1021/cr300182k · Cited by 2,886
Organic Solvent Effects in Biomass Conversion Reactions
Shuai, L., & Luterbacher, J. (2016) · ChemSusChem · doi:10.1002/cssc.201501148 · Cited by 445
Hu, L., Lin, L., Wu, Z., Zhou, S., & Liu, S. (2017) · Renewable and Sustainable Energy Reviews · doi:10.1016/j.rser.2017.02.042 · Cited by 445
Activation of Carbonyl-Containing Molecules with Solid Lewis Acids in Aqueous Media
Román-Leshkov, Y., & Davis, M. E. (2011) · ACS Catalysis · doi:10.1021/cs200411d · Cited by 401
Self-citationHeterogeneous Catalysis for Tandem Reactions
Climent, M. J., Corma, A., Iborra, S., & Sabater, M. J. (2014) · ACS Catalysis · doi:10.1021/cs401052k · Cited by 361
Metadata
- Authors
- Nikolla, E., Román-Leshkov, Y., Moliner, M., & Davis, M. E.
- Venue
- ACS Catalysis
- Publisher
- American Chemical Society (ACS)
- Published
- 2011-03-11
- Volume
- 1
- Issue
- 4
- Pages
- 408-410
- ISSN
- 2155-5435 (ISSN-L)
- OpenAlex
- W2048704620
- Cited by
- 674
- References
- 2
- FWCI
- 31.00
- Type
- journal article
- Language
- en
- Open access
- green
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