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Palladium–Tin Alloyed Catalysts for the Ethanol Oxidation Reaction in an Alkaline Medium
Abstract
In this paper, we present a study of a series of carbon-supported Pd–Sn binary alloyed catalysts prepared through a modified Polyol method as anode electrocatalysts for direct ethanol fuel cell reactions in an alkaline medium. Transmission electron microscopy, energy-dispersive X-ray spectroscopy, X-ray diffraction, X-ray photoelectron spectroscopy, and aberration-corrected scanning transmission electron microscopy equipped with electron energy loss spectroscopy were used to characterize the Pd–Sn/C catalysts, where homogeneous Pd–Sn alloys were determined to be present with the surface Sn being partially oxidized. Among various Pd–Sn catalysts, Pd 86 Sn 14 /C catalysts showed much enhanced current densities in cyclic voltammetric and chronoamperometric measurements, compared to commercial Pd/C (Johnson Matthey). The overall rate law of ethanol oxidation reaction for both Pd 86 Sn 14 /C and commercial Pd/C were also determined, which clearly showed that Pd 86 Sn 14 /C was more favorable in high ethanol concentration and/or high pH environment. Density functional theory calculations also confirmed Pd–Sn alloy structures would result in lower reaction energies for the dehydrogenation of ethanol, compared to the pure Pd crystal.
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Citations
Cites
Generalized Gradient Approximation Made Simple
Perdew, J. P., Burke, K., & Ernzerhof, M. (1996) · Physical Review Letters · doi:10.1103/physrevlett.77.3865 · Cited by 215,824
Separable dual-space Gaussian pseudopotentials
Goedecker, S., Teter, M., & Hutter, J. (1996) · Physical Review B · doi:10.1103/physrevb.54.1703 · Cited by 7,479
VandeVondele, J., Krack, M., Mohamed, F., Parrinello, M., Chassaing, T., & Hutter, J. (2005) · Computer Physics Communications · doi:10.1016/j.cpc.2004.12.014 · Cited by 5,822
Pseudopotentials for H to Kr optimized for gradient-corrected exchange-correlation functionals
Krack, M. (2005) · Theoretical Chemistry Accounts · doi:10.1007/s00214-005-0655-y · Cited by 1,739
Bianchini, C., & Shen, P. K. (2009) · Chemical Reviews · doi:10.1021/cr9000995 · Cited by 1,626
A hybrid Gaussian and plane wave density functional scheme
LIPPERT, G., HUTTER, J., & PARRINELLO, M. (1997) · Molecular Physics · doi:10.1080/00268979709482119 · Cited by 1,377
The oxidation of small organic molecules
Parsons, R., & VanderNoot, T. (1988) · Journal of Electroanalytical Chemistry and Interfacial Electrochemistry · doi:10.1016/0022-0728(88)87028-1 · Cited by 1,207
A hybrid Gaussian and plane wave density functional scheme
LIPPERT, B. G., & Hutter, J. (1997) · Molecular Physics · doi:10.1080/002689797170220 · Cited by 949
Alkaline direct alcohol fuel cells
Antolini, E., & Gonzalez, E. R. (2010) · Journal of Power Sources · doi:10.1016/j.jpowsour.2009.11.145 · Cited by 898
Mechanism study of the ethanol oxidation reaction on palladium in alkaline media
Liang, Z. X., Zhao, T. S., Xu, J. B., & Zhu, L. D. (2009) · Electrochimica Acta · doi:10.1016/j.electacta.2008.10.034 · Cited by 842
Electrocatalysis of oxygen reduction and small alcohol oxidation in alkaline media
Spendelow, J. S., & Wieckowski, A. (2007) · Physical Chemistry Chemical Physics · doi:10.1039/b703315j · Cited by 821
Ternary Pt/Rh/SnO2 electrocatalysts for oxidizing ethanol to CO2
Kowal, A., Li, M., Shao, M., Sasaki, K., Vukmirovic, M. B., Zhang, J., Marinkovic, N. S., Liu, P., Frenkel, A. I., & Adzic, R. R. (2009) · Nature Materials · doi:10.1038/nmat2359 · Cited by 784
B IOMASS E THANOL: Technical Progress, Opportunities, and Commercial Challenges
Wyman, C. E. (1999) · Annual Review of Energy and the Environment · doi:10.1146/annurev.energy.24.1.189 · Cited by 601
Electrocatalytic oxidation of aliphatic alcohols: Application to the direct alcohol fuel cell (DAFC)
Lamy, C., Belgsir, E. M., & Léger, J.-M. (2001) · Journal of Applied Electrochemistry · doi:10.1023/a:1017587310150 · Cited by 589
Vigier, F., Coutanceau, C., Hahn, F., Belgsir, E. M., & Lamy, C. (2004) · Journal of Electroanalytical Chemistry · doi:10.1016/j.jelechem.2003.08.019 · Cited by 547
Electrocatalytic Activity of Ordered Intermetallic Phases for Fuel Cell Applications
Casado-Rivera, E., Volpe, D. J., Alden, L., Lind, C., Downie, C., Vázquez-Alvarez, T., Angelo, A. C. D., DiSalvo, F. J., & Abruña, H. D. (2004) · Journal of the American Chemical Society · doi:10.1021/ja038497a · Cited by 521
Xu, C. W., Wang, H., Shen, P. K., & Jiang, S. P. (2007) · Advanced Materials · doi:10.1002/adma.200602911 · Cited by 494
Alcohol oxidation on nanocrystalline oxide Pd/C promoted electrocatalysts
Shen, P. K., & Xu, C. (2006) · Electrochemistry Communications · doi:10.1016/j.elecom.2005.11.013 · Cited by 394
de Souza, J. P. I., Queiroz, S. L., Bergamaski, K., Gonzalez, E. R., & Nart, F. C. (2002) · The Journal of Physical Chemistry B · doi:10.1021/jp014645c · Cited by 390
Lu, C.-L., Prasad, K. S., Wu, H.-L., Ho, J.-A. A., & Huang, M. H. (2010) · Journal of the American Chemical Society · doi:10.1021/ja105401p · Cited by 389
Conversion of hydrocarbons and alcohols for fuel cells
Joensen, F., & Rostrup-Nielsen, J. R. (2002) · Journal of Power Sources · doi:10.1016/s0378-7753(01)00939-9 · Cited by 357
Enhancement effect of Ag for Pd/C towards the ethanol electro-oxidation in alkaline media
Nguyen, S. T., Law, H. M., Nguyen, H. T., Kristian, N., Wang, S., Chan, S. H., & Wang, X. (2009) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2009.06.021 · Cited by 341
Recent advances in fuel cell technology and its applications
Acres, G. (2001) · Journal of Power Sources · doi:10.1016/s0378-7753(01)00883-7 · Cited by 323
A kinetic analysis of the electro-oxidation of ethanol at a platinum electrode in acid medium
Hitmi, H., Belgsir, E. M., Léger, J.-M., Lamy, C., & Lezna, R. O. (1994) · Electrochimica Acta · doi:10.1016/0013-4686(94)80080-4 · Cited by 284
Structure and chemical composition of supported Pt–Sn electrocatalysts for ethanol oxidation
Jiang, L., Sun, G., Sun, S., Liu, J., Tang, S., Li, H., Zhou, B., & Xin, Q. (2005) · Electrochimica Acta · doi:10.1016/j.electacta.2005.03.018 · Cited by 280
Varcoe, J. R., Slade, R. C. T., & Lam How Yee, E. (2006) · Chemical Communications · doi:10.1039/b600838k · Cited by 267
Development of electrocatalysts for solid alkaline fuel cell (SAFC)
Coutanceau, C., Demarconnay, L., Lamy, C., & Léger, J.-M. (2006) · Journal of Power Sources · doi:10.1016/j.jpowsour.2005.08.035 · Cited by 211
Kheshgi, H. S., Prince, R. C., & Marland, G. (2000) · Annual Review of Energy and the Environment · doi:10.1146/annurev.energy.25.1.199 · Cited by 208
Ethanol electrooxidation on novel carbon supported Pt/SnOx/C catalysts with varied Pt:Sn ratio
Jiang, L., Colmenares, L., Jusys, Z., Sun, G. Q., & Behm, R. J. (2007) · Electrochimica Acta · doi:10.1016/j.electacta.2007.01.047 · Cited by 205
He, Q., Chen, W., Mukerjee, S., Chen, S., & Laufek, F. (2009) · Journal of Power Sources · doi:10.1016/j.jpowsour.2008.11.065 · Cited by 202
Du, W., Wang, Q., Saxner, D., Deskins, N. A., Su, D., Krzanowski, J. E., Frenkel, A. I., & Teng, X. (2011) · Journal of the American Chemical Society · doi:10.1021/ja205649z · Cited by 182
Self-citationBianchini, C., Bambagioni, V., Filippi, J., Marchionni, A., Vizza, F., Bert, P., & Tampucci, A. (2009) · Electrochemistry Communications · doi:10.1016/j.elecom.2009.03.022 · Cited by 161
Antolini, E., & Gonzalez, E. R. (2010) · Catalysis Today · doi:10.1016/j.cattod.2010.07.018 · Cited by 152
First-Principles Considerations on Catalytic Activity of Pd toward Ethanol Oxidation
Cui, G., Song, S., Shen, P. K., Kowal, A. T., & Bianchini, C. (2009) · The Journal of Physical Chemistry C · doi:10.1021/jp900924s · Cited by 125
Non-Pt Anode Catalysts for Alkaline Direct Alcohol Fuel Cells
Chen, Y., Zhuang, L., & Lu, J. (2007) · CHINESE JOURNAL OF CATALYSIS (CHINESE VERSION) · doi:10.1016/s1872-2067(07)60073-4 · Cited by 87
Antolini, E., & Gonzalez, E. R. (2010) · Electrochimica Acta · doi:10.1016/j.electacta.2010.08.077 · Cited by 86
Antolini, E., Zignani, S. C., Santos, S. F., & Gonzalez, E. R. (2010) · Electrochimica Acta · doi:10.1016/j.electacta.2010.11.101 · Cited by 82
Prakash, G. K. S., Krause, F. C., Viva, F. A., Narayanan, S. R., & Olah, G. A. (2011) · Journal of Power Sources · doi:10.1016/j.jpowsour.2011.05.056 · Cited by 66
Du, W., Wang, Q., LaScala, C. A., Zhang, L., Su, D., Frenkel, A. I., Mathur, V. K., & Teng, X. (2011) · Journal of Materials Chemistry · doi:10.1039/c0jm04358c · Cited by 61
Self-citationKang, W.-D., Wei, Y.-C., Liu, C.-W., & Wang, K. (2010) · Electrochemistry Communications · doi:10.1016/j.elecom.2010.12.003 · Cited by 42
The Ethanol Answer to Carbon Emissions
Lave, L. B., Griffin, W. M., & MacLean, H. L. (2018) · KiltHub Repository · doi:10.1184/r1/6708461 · Cited by 38
Du, W., Su, D., Wang, Q., Frenkel, A. I., & Teng, X. (2011) · Crystal Growth & Design · doi:10.1021/cg1015093 · Cited by 38
Self-citation
Cited by
Chen, M., Duan, Y., chen, F., Zheng, W., Yang, W., & Tian, M. (2023) · Energy & Fuels · doi:10.1021/acs.energyfuels.2c03601 · Cited by 9
Metadata
- Authors
- Du, W., Mackenzie, K. E., Milano, D. F., Deskins, N. A., Su, D., & Teng, X.
- Venue
- ACS Catalysis
- Publisher
- American Chemical Society (ACS)
- Published
- 2012-01-24
- Volume
- 2
- Issue
- 2
- Pages
- 287-297
- ISSN
- 2155-5435 (ISSN-L)
- OpenAlex
- W1996664931
- Cited by
- 306
- References
- 42
- FWCI
- 6.92
- Type
- journal article
- Language
- en
- Open access
- closed
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