The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
Production of 5-Hydroxymethylfurfural from Glucose Using a Combination of Lewis and Brønsted Acid Catalysts in Water in a Biphasic Reactor with an Alkylphenol Solvent
Abstract
We report the catalytic conversion of glucose in high yields (62%) to 5-hydroxymethylfurfural (HMF), a versatile platform chemical. The reaction system consists of a Lewis acid metal chloride (e.g., AlCl 3 ) and a Brønsted acid (HCl) in a biphasic reactor consisting of water and an alkylphenol compound (2- sec -butylphenol) as the organic phase. The conversion of glucose in the presence of Lewis and Brønsted acidity proceeds through a tandem pathway involving isomerization of glucose to fructose, followed by dehydration of fructose to HMF. The organic phase extracts 97% of the HMF produced, while both acid catalysts remain in the aqueous phase.
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Citations
Cites
Chemical Routes for the Transformation of Biomass into Chemicals
Corma, A., Iborra, S., & Velty, A. (2007) · Chemical Reviews · doi:10.1021/cr050989d · Cited by 5,970
Metal Chlorides in Ionic Liquid Solvents Convert Sugars to 5-Hydroxymethylfurfural
Zhao, H., Holladay, J. E., Brown, H., & Zhang, Z. C. (2007) · Science · doi:10.1126/science.1141199 · Cited by 1,997
Cited by
Hydroxymethylfurfural, A Versatile Platform Chemical Made from Renewable Resources
van Putten, R.-J., van der Waal, J. C., de Jong, E., Rasrendra, C. B., Heeres, H. J., & de Vries, J. G. (2013) · Chemical Reviews · doi:10.1021/cr300182k · Cited by 2,886
Catalytic conversion of lignocellulosic biomass into chemicals and fuels
Deng, W., Feng, Y., Fu, J., Guo, H., Guo, Y., Han, B., Jiang, Z., Kong, L., Li, C., Liu, H., et al. (2023) · Green Energy & Environment · doi:10.1016/j.gee.2022.07.003 · Cited by 854
From lignocellulosic biomass to levulinic acid: A review on acid-catalyzed hydrolysis
Kang, S., Fu, J., & Zhang, G. (2018) · Renewable and Sustainable Energy Reviews · doi:10.1016/j.rser.2018.06.016 · Cited by 580
Organic Solvent Effects in Biomass Conversion Reactions
Shuai, L., & Luterbacher, J. (2016) · ChemSusChem · doi:10.1002/cssc.201501148 · Cited by 445
Organocatalysis in biorefining for biomass conversion and upgrading
Liu, D. (. J. )., & Chen, E. Y.-X. (2014) · Green Chem. · doi:10.1039/c3gc41934g · Cited by 101
Metadata
- Authors
- Pagán-Torres, Y. J., Wang, T., Gallo, J. M. R., Shanks, B. H., & Dumesic, J. A.
- Venue
- ACS Catalysis
- Publisher
- American Chemical Society (ACS)
- Published
- 2012-04-26
- Volume
- 2
- Issue
- 6
- Pages
- 930-934
- ISSN
- 2155-5435 (ISSN-L)
- OpenAlex
- W2125526377
- Cited by
- 512
- References
- 2
- FWCI
- 21.63
- Type
- journal article
- Language
- en
- Open access
- closed
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