The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
Heterogeneous Catalysis on Atomically Dispersed Supported Metals: CO2 Reduction on Multifunctional Pd Catalysts
Abstract
Because of their heterogeneous nature, supported metal catalysts always contain metal centers in a rather broad dispersion range, and the presence of even atomically dispersed metals has been reported on oxide supports. The role of the atomically dispersed metal centers in the overall catalytic performances of these supported metal catalysts, however, has not been addressed to date. In this study, temperature programmed reaction and scanning transmission electron microscopy experiments were applied to show the fundamentally different reactivity patterns exhibited by Pd metal in atomically dispersed and traditional 3D clusters in the demanding reaction of CO 2 reduction. The requirement for two different catalyst functionalities in the reduction of CO 2 with hydrogen on Pd/Al 2 O 3 and Pd/MWCNT catalysts was also substantiated. The results obtained clearly show that the oxide support material, even when it is considered inert like Al 2 O 3, can function as a critical, active component of complex catalyst systems.
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Cites
How copper catalyzes the electroreduction of carbon dioxide into hydrocarbon fuels
Peterson, A. A., Abild-Pedersen, F., Studt, F., Rossmeisl, J., & Nørskov, J. K. (2010) · Energy & Environmental Science · doi:10.1039/c0ee00071j · Cited by 3,784
Recent advances in catalytic hydrogenation of carbon dioxide
Wang, W., Wang, S., Ma, X., & Gong, J. (2011) · Chemical Society Reviews · doi:10.1039/c1cs15008a · Cited by 3,316
Cited by
Li, S., Xu, Y., Chen, Y., Li, W., Lin, L., Li, M., Deng, Y., Wang, X., Ge, B., Yang, C., et al. (2017) · Angewandte Chemie International Edition · doi:10.1002/anie.201705002 · Cited by 523
Single-Atom Catalysis toward Efficient CO2 Conversion to CO and Formate Products
Su, X., Yang, X.-F., Huang, Y., Liu, B., & Zhang, T. (2019) · Accounts of Chemical Research · doi:10.1021/acs.accounts.8b00478 · Cited by 499
Nong, S., Dong, W., Yin, J., Dong, B., Lu, Y., Yuan, X., Wang, X., Bu, K., Chen, M., Jiang, S., et al. (2018) · Journal of the American Chemical Society · doi:10.1021/jacs.7b13736 · Cited by 312
Metal/Oxide Interface Nanostructures Generated by Surface Segregation for Electrocatalysis
Weng, Z., Liu, W., Yin, L.-C., Fang, R., Li, M., Altman, E. I., Fan, Q., Li, F., Cheng, H.-M., & Wang, H. (2015) · Nano Letters · doi:10.1021/acs.nanolett.5b03709 · Cited by 278
Pulsed Laser in Liquids Made Nanomaterials for Catalysis
Forsythe, R. C., Cox, C. P., Wilsey, M. K., & Müller, A. M. (2021) · Chemical Reviews · doi:10.1021/acs.chemrev.0c01069 · Cited by 259
Metadata
- Authors
- Kwak, J. H., Kovarik, L., & Szanyi, J.
- Venue
- ACS Catalysis
- Publisher
- American Chemical Society (ACS)
- Published
- 2013-08-16
- Volume
- 3
- Issue
- 9
- Pages
- 2094-2100
- ISSN
- 2155-5435 (ISSN-L)
- OpenAlex
- W2323239271
- Cited by
- 388
- References
- 2
- FWCI
- 6.07
- Type
- journal article
- Language
- en
- Open access
- closed
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