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Cited by 172

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Studies on the Vanadium-Catalyzed Nonoxidative Depolymerization of Miscanthus giganteus-Derived Lignin

Chan, Julian M. W., Bauer, Stefan, Sorek, Hagit, Sreekumar, Sanil, Wang, Kun, Toste, F. Dean·2013·ACS Catalysis

Abstract

Lignin samples isolated from Miscanthus giganteus using organosolv processes were treated with vanadium catalysts that were previously developed in our group. We demonstrate that the catalyst with high β-O-4′ bond-cleaving activity in dimeric lignin models was also effective in depolymerizing actual lignin. Molecular weight-lowering was evidenced by gel permeation chromatography (GPC), whereas 2D NMR experiments showed that β-O-4′ linkages were selectively cleaved in the degradation process, just as in the case of lignin models. Monophenolic degradation products were also formed, and the individual molecules were identified and quantified by GC/MS.

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Metadata

Authors
Chan, J. M. W., Bauer, S., Sorek, H., Sreekumar, S., Wang, K., & Toste, F. D.
Venue
ACS Catalysis
Published
2013-05-21
Volume
3
Issue
6
Pages
1369-1377
ISSN
2155-5435 (ISSN-L)
OpenAlex
W2126571061
Cited by
172
References
3
FWCI
11.87
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Studies on the Vanadium-Catalyzed Nonoxidative Depolymerization of Miscanthus giganteus-Derived Lignin. https://app.cochat.ai/papers/10.1021/cs400333q
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Chan, J. M. W., Bauer, S., Sorek, H., Sreekumar, S., Wang, K., & Toste, F. D. (2013). Studies on the Vanadium-Catalyzed Nonoxidative Depolymerization of Miscanthus giganteus-Derived Lignin. ACS Catalysis. https://doi.org/10.1021/cs400333q

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