The DOI matches its Crossref record; 4 of the 4 references it cites were found in a registry or an index.
Highly Asymmetric Phthalocyanine as a Sensitizer of Graphitic Carbon Nitride for Extremely Efficient Photocatalytic H2 Production under Near-Infrared Light
Abstract
Highly asymmetric zinc phthalocyanine derivative (Zn- tri -PcNc) with intense near-IR light (650–800 nm) absorption is utilized as a sensitizer to extend the spectral response region of graphitic carbon nitride (g-C 3 N 4 ) from ∼450 nm to more than 800 nm. Ultraviolet–visible light (UV-vis) diffuse reflectance absorption spectra (DRS), photoluminescence (PL) spectra, time-resolved photoluminescence spectra (TRPS), and energy band structure analyses are adopted to investigate the photogenerated electron transfer process between Zn- tri -PcNc and g-C 3 N 4 on both thermodynamics and dynamics aspects. After optimizing the photocatalytic condition and adding chenodeoxycholic acid (CDCA) as coadsorbent, Zn- tri -PcNc sensitized g-C 3 N 4 photocatalyst shows a H 2 production efficiency of 125.2 μmol h –1 under visible/near-IR-light (λ ≥ 500 nm) irradiation, corresponding to a turnover number (TON) of 5008 h –1 with an extremely high apparent quantum yield (AQY) of 1.85% at 700 nm monochromatic light irradiation. The present work should be the rarely fundamental investigation on the utilization of near-IR light of solar radiation for the photocatalytic H 2 production from water splitting over a dye-sensitized semiconductor.
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Cites
Semiconductor-based Photocatalytic Hydrogen Generation
Chen, X., Shen, S., Guo, L., & Mao, S. S. (2010) · Chemical Reviews · doi:10.1021/cr1001645 · Cited by 7,876
TiO2 photocatalysis: Design and applications
Nakata, K., & Fujishima, A. (2012) · Journal of Photochemistry and Photobiology C: Photochemistry Reviews · doi:10.1016/j.jphotochemrev.2012.06.001 · Cited by 3,651
Progress, challenge and perspective of heterogeneous photocatalysts
Qu, Y., & Duan, X. (2013) · Chem. Soc. Rev. · doi:10.1039/c2cs35355e · Cited by 1,466
Abe, R. (2010) · Journal of Photochemistry and Photobiology C: Photochemistry Reviews · doi:10.1016/j.jphotochemrev.2011.02.003 · Cited by 1,223
Cited by
Ong, W.-J., Tan, L.-L., Ng, Y. H., Yong, S.-T., & Chai, S.-P. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00075 · Cited by 7,147
Metal-free efficient photocatalyst for stable visible water splitting via a two-electron pathway
Liu, J., Liu, Y., Liu, N., Han, Y., Zhang, X., Huang, H., Lifshitz, Y., Lee, S.-T., Zhong, J., & Kang, Z. (2015) · Science · doi:10.1126/science.aaa3145 · Cited by 4,468
Self-citationEngineering heterogeneous semiconductors for solar water splitting
Li, X., Yu, J., Low, J., Fang, Y., Xiao, J., & Chen, X. (2015) · Journal of Materials Chemistry A · doi:10.1039/c4ta04461d · Cited by 1,888
Self-citationLiao, G., Gong, Y., Zhang, L., Gao, H., Yang, G.-J., & Fang, B. (2019) · Energy & Environmental Science · doi:10.1039/c9ee00717b · Cited by 1,075
Recent advances in dye-sensitized semiconductor systems for photocatalytic hydrogen production
Zhang, X., Peng, T., & Song, S. (2016) · Journal of Materials Chemistry A · doi:10.1039/c5ta08939e · Cited by 434
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Metadata
- Authors
- Zhang, X., Yu, L., Zhuang, C., Peng, T., Li, R., & Li, X.
- Venue
- ACS Catalysis
- Publisher
- American Chemical Society (ACS)
- Published
- 2013-12-11
- Volume
- 4
- Issue
- 1
- Pages
- 162-170
- ISSN
- 2155-5435 (ISSN-L)
- OpenAlex
- W2312700749
- Cited by
- 291
- References
- 4
- FWCI
- 7.33
- Type
- journal article
- Language
- en
- Open access
- closed
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- Zhang, X., Yu, L., Zhuang, C., Peng, T., Li, R., & Li, X. (2014). Highly Asymmetric Phthalocyanine as a Sensitizer of Graphitic Carbon Nitride for Extremely Efficient Photocatalytic H2 Production under Near-Infrared Light. ACS Catalysis. https://doi.org/10.1021/cs400863c
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