The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
A Series of NiM (M = Ru, Rh, and Pd) Bimetallic Catalysts for Effective Lignin Hydrogenolysis in Water
Open accessAbstract
In this paper, NiRu, NiRh, and NiPd catalysts were synthesized and evaluated in the hydrogenolysis of lignin C–O bonds, which is proved to be superior over single-component catalysts. The optimized NiRu catalyst contains 85% Ni and 15% Ru, composed of Ni surface-enriched, Ru–Ni atomically mixed, ultrasmall nanoparticles. The Ni 85 Ru 15 catalyst showed high activity under low temperature (100 °C), low H 2 pressure (1 bar) in β-O-4 type C–O bond hydrogenolysis. It also exhibited significantly higher activity over Ni and Ru catalysts in the direct conversion of lignin into monomeric aromatic chemicals. Mechanistic investigation indicates that the synergistic effect of NiRu can be attributed to three factors: (1) increased fraction of surface atoms (compared with Ni), (2) enhanced H 2 and substrate activation (compared with Ni), and (3) inhibited benzene ring hydrogenation (compared with Ru). Similarly, NiRh and NiPd catalysts were more active and selective than their single-component counterparts in the hydrogenolysis of lignin model compounds and real lignin.
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Citations
Cites
Chemical Routes for the Transformation of Biomass into Chemicals
Corma, A., Iborra, S., & Velty, A. (2007) · Chemical Reviews · doi:10.1021/cr050989d · Cited by 5,970
Conversion of Biomass into Chemicals over Metal Catalysts
Besson, M., Gallezot, P., & Pinel, C. (2014) · Chemical Reviews · doi:10.1021/cr4002269 · Cited by 1,780
Holladay, J. E., White, J. F., Bozell, J. J., & Johnson, D. (2007) · doi:10.2172/921839 · Cited by 905
Cited by
Catalytic Transformation of Lignin for the Production of Chemicals and Fuels
Li, C., Zhao, X., Wang, A., Huber, G. W., & Zhang, T. (2015) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00155 · Cited by 2,951
Catalytic conversion of lignocellulosic biomass into chemicals and fuels
Deng, W., Feng, Y., Fu, J., Guo, H., Guo, Y., Han, B., Jiang, Z., Kong, L., Li, C., Liu, H., et al. (2023) · Green Energy & Environment · doi:10.1016/j.gee.2022.07.003 · Cited by 854
Self-citationDownstream processing of lignin derived feedstock into end products
Wong, S. S., Shu, R., Zhang, J., Liu, H., & Yan, N. (2020) · Chemical Society Reviews · doi:10.1039/d0cs00134a · Cited by 528
Self-citationLignin depolymerization into aromatic monomers over solid acid catalysts
Deepa, A. K., & Dhepe, P. L. (2015) · ACS Catalysis · doi:10.1021/cs501371q · Cited by 346
Deng, W., Zhang, H., Wu, X., Li, R., Zhang, Q., & Wang, Y. (2015) · Green Chemistry · doi:10.1039/c5gc01473e · Cited by 272
Metadata
- Authors
- Zhang, J., Teo, J., Chen, X., Asakura, H., Tanaka, T., Teramura, K., & Yan, N.
- Venue
- ACS Catalysis
- Publisher
- American Chemical Society (ACS)
- Published
- 2014-04-18
- Volume
- 4
- Issue
- 5
- Pages
- 1574-1583
- ISSN
- 2155-5435 (ISSN-L)
- OpenAlex
- W2334811823
- Cited by
- 492
- References
- 3
- FWCI
- 25.82
- Type
- journal article
- Language
- en
- Open access
- green
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- Zhang, J., Teo, J., Chen, X., Asakura, H., Tanaka, T., Teramura, K., & Yan, N. (2014). A Series of NiM (M = Ru, Rh, and Pd) Bimetallic Catalysts for Effective Lignin Hydrogenolysis in Water. ACS Catalysis. https://doi.org/10.1021/cs401199f
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