The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Highly Selective Production of Hydrogen Peroxide on Graphitic Carbon Nitride (g-C3N4) Photocatalyst Activated by Visible Light
Open accessAbstract
High Resolution Image Download MS PowerPoint Slide Photocatalytic production of hydrogen peroxide (H 2 O 2 ) on semiconductor catalysts with alcohol as a hydrogen source and molecular oxygen (O 2 ) as an oxygen source is a potential method for safe H 2 O 2 synthesis because the reaction can be carried out without the use of explosive H 2 /O 2 mixed gases. Early reported photocatalytic systems, however, produce H 2 O 2 with significantly low selectivity (∼1%). We found that visible light irradiation (λ > 420 nm) of graphitic carbon nitride (g-C 3 N 4 ), a polymeric semiconductor, in an alcohol/water mixture with O 2 efficiently produces H 2 O 2 with very high selectivity (∼90%). Raman spectroscopy and electron spin resonance analysis revealed that the high H 2 O 2 selectivity is due to the efficient formation of 1,4-endoperoxide species on the g-C 3 N 4 surface. This suppresses one-electron reduction of O 2 (superoxide radical formation), resulting in selective promotion of two-electron reduction of O 2 (H 2 O 2 formation).
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Cites
Cui, Y., Ding, Z., Liu, P., Antonietti, M., Fu, X., & Wang, X. (2012) · Phys. Chem. Chem. Phys. · doi:10.1039/c1cp22820j · Cited by 585
Cited by
Ong, W.-J., Tan, L.-L., Ng, Y. H., Yong, S.-T., & Chai, S.-P. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00075 · Cited by 7,147
Kofuji, Y., Isobe, Y., Shiraishi, Y., Sakamoto, H., Tanaka, S., Ichikawa, S., & Hirai, T. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.6b05806 · Cited by 587
Self-citationZeng, X., Liu, Y., Kang, Y., Li, Q., Xia, Y., Zhu, Y., Hou, H., Uddin, M. H., Gengenbach, T. R., Xia, D., et al. (2020) · ACS Catalysis · doi:10.1021/acscatal.9b05247 · Cited by 482
Yang, Y., Zeng, G., Huang, D., Zhang, C., He, D., Zhou, C., Wang, W., Xiong, W., Li, X., Li, B., et al. (2020) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2020.118970 · Cited by 412
Jiang, D., Li, J., Xing, C., Zhang, Z., Meng, S., & Chen, M. (2015) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.5b05118 · Cited by 328
Zheng, Q., Durkin, D. P., Elenewski, J. E., Sun, Y., Banek, N. A., Hua, L., Chen, H., Wagner, M. J., Zhang, W., & Shuai, D. (2016) · Environmental Science & Technology · doi:10.1021/acs.est.6b02579 · Cited by 328
Cao, J., Wang, H., Zhao, Y., Liu, Y., Wu, Q., Huang, H., Shao, M., Liu, Y., & Kang, Z. (2020) · Journal of Materials Chemistry A · doi:10.1039/c9ta13929j · Cited by 136
Metadata
- Authors
- Shiraishi, Y., Kanazawa, S., Sugano, Y., Tsukamoto, D., Sakamoto, H., Ichikawa, S., & Hirai, T.
- Venue
- ACS Catalysis
- Publisher
- American Chemical Society (ACS)
- Published
- 2014-02-07
- Volume
- 4
- Issue
- 3
- Pages
- 774-780
- ISSN
- 2155-5435 (ISSN-L)
- OpenAlex
- W2331310204
- Cited by
- 829
- References
- 1
- FWCI
- 10.37
- Type
- journal article
- Language
- en
- Open access
- hybrid
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