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Cited by 171

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Dye-Sensitized NiSx Catalyst Decorated on Graphene for Highly Efficient Reduction of Water to Hydrogen under Visible Light Irradiation

Kong, Chao, Min, Shixiong, Lu, Gongxuan·2014·ACS Catalysis

Abstract

In this work, a highly active H 2 evolution NiS x catalyst decorated on graphene (NiS x /G) nanohybrid was prepared by an in situ chemical deposition method, in which nickel ion was first adsorbed onto graphene and subsequently reacted with sulfide ion to yield the NiS x /G nanohybrid. The NiS x /G catalyst exhibited activity for hydrogen generation 2-fold higher than that of pristine NiS x under visible light irradiation. The highest quantum efficiency of 32.5% was reached at 430 nm when Eosin Y was used as a photosensitizer. In this system, graphene not only provided a large area and two-dimensional substrate for the confined growth of NiS x but also greatly enhanced the transfer of photoelectrons from excited Eosin Y to the NiS x cocatalyst because of its promotion of charge separation, leading to the great enhancement of photocatalytic hydrogen evolution.

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Metadata

Authors
Kong, C., Min, S., & Lu, G.
Venue
ACS Catalysis
Published
2014-07-21
Volume
4
Issue
8
Pages
2763-2769
ISSN
2155-5435 (ISSN-L)
OpenAlex
W2325696345
Cited by
171
References
1
FWCI
7.86
Type
journal article
Language
en
Open access
closed

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