The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Selective Base-Catalyzed Isomerization of Glucose to Fructose
Abstract
Fructose is a key intermediate in the conversion of cellulosic biomass to biofuels and renewable platform chemicals. Biomass-derived glucose can be isomerized to fructose using either Lewis acid or Brønsted base catalysts. Lewis acids are typically preferred as alkaline conditions promote a large number of side reactions. It is widely admitted that only low fructose yields, below 10%, are achievable with inorganic bases. Here, fructose was synthesized with 32% yield using commercially available organic amines. Glucose conversion and fructose selectivity were comparable to Lewis acids, which opens new perspectives for the base-catalyzed pathway.
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Cites
Hydroxymethylfurfural, A Versatile Platform Chemical Made from Renewable Resources
van Putten, R.-J., van der Waal, J. C., de Jong, E., Rasrendra, C. B., Heeres, H. J., & de Vries, J. G. (2013) · Chemical Reviews · doi:10.1021/cr300182k · Cited by 2,886
Cited by
Catalytic oxidation of carbohydrates into organic acids and furan chemicals
Zhang, Z., & Huber, G. W. (2018) · Chemical Society Reviews · doi:10.1039/c7cs00213k · Cited by 689
Catalytic Isomerization of Biomass‐Derived Aldoses: A Review
Delidovich, I., & Palkovits, R. (2016) · ChemSusChem · doi:10.1002/cssc.201501577 · Cited by 300
Chen, S. S., Maneerung, T., Tsang, D. C. W., Ok, Y. S., & Wang, C.-H. (2017) · Chemical Engineering Journal · doi:10.1016/j.cej.2017.07.020 · Cited by 258
Metadata
- Authors
- Liu, C., Carraher, J. M., Swedberg, J. L., Herndon, C. R., Fleitman, C. N., & Tessonnier, J.-P.
- Venue
- ACS Catalysis
- Publisher
- American Chemical Society (ACS)
- Published
- 2014-11-05
- Volume
- 4
- Issue
- 12
- Pages
- 4295-4298
- ISSN
- 2155-5435 (ISSN-L)
- OpenAlex
- W2326657197
- Cited by
- 203
- References
- 1
- FWCI
- 6.29
- Type
- journal article
- Language
- en
- Open access
- closed
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- Liu, C., Carraher, J. M., Swedberg, J. L., Herndon, C. R., Fleitman, C. N., & Tessonnier, J.-P. (2014). Selective Base-Catalyzed Isomerization of Glucose to Fructose. ACS Catalysis. https://doi.org/10.1021/cs501197w
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