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Catalyst Evaluation for Catalytic Biomass Pyrolysis
Abstract
Commercial catalysts, including zeolites (HZSM-5), fluid catalytic cracking (FCC) catalysts, transition metal catalysts (Fe/Cr), and aluminas, were successfully evaluated in a fixed bed catalytic reactor using a mixture of model compounds to simulate biomass flash pyrolysis vapors. Successful criteria including the stability index (SI), the water generation (WG), and the loss of organics (LO) were introduced to monitor the effect of catalysts and ascertain major changes in the obtained liquid product composition. SI being a measure of the effective carbonyls reduction after catalytic cracking reached 100% in the case of HZSM-5 catalysts, leading to the selective production of aromatic hydrocarbons. Transition metal catalysts (Fe/Cr) lead to the selective production of phenol and light phenolics. Comparable trends were obtained using solid biomass in the catalytic fixed bed reactor.
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Cited by
Effect of process parameters on production of biochar from biomass waste through pyrolysis: A review
Tripathi, M., Sahu, J. N., & Ganesan, P. (2016) · Renewable and Sustainable Energy Reviews · doi:10.1016/j.rser.2015.10.122 · Cited by 1,759
Al-Rumaihi, A., Shahbaz, M., Mckay, G., Mackey, H., & Al-Ansari, T. (2022) · Renewable and Sustainable Energy Reviews · doi:10.1016/j.rser.2022.112715 · Cited by 650
Ghodake, G. S., Shinde, S. K., Kadam, A. A., Saratale, R. G., Saratale, G. D., Kumar, M., Palem, R. R., AL-Shwaiman, H. A., Elgorban, A. M., Syed, A., et al. (2021) · Journal of Cleaner Production · doi:10.1016/j.jclepro.2021.126645 · Cited by 414
Controlling the selectivity to chemicals from lignin via catalytic fast pyrolysis
Ma, Z., Troussard, E., & van Bokhoven, J. A. (2012) · Applied Catalysis A: General · doi:10.1016/j.apcata.2012.02.027 · Cited by 363
Catalytic pyrolysis of lignocellulosic biomass for bio-oil production: A review
Wang, Y., Akbarzadeh, A., Chong, L., Du, J., Tahir, N., & Awasthi, M. K. (2022) · Chemosphere · doi:10.1016/j.chemosphere.2022.134181 · Cited by 247
Metadata
- Authors
- Samolada, M. C., Papafotica, A., & Vasalos, I. A.
- Venue
- Energy & Fuels
- Publisher
- American Chemical Society (ACS)
- Published
- 2000-09-12
- Volume
- 14
- Issue
- 6
- Pages
- 1161-1167
- ISSN
- 0887-0624 (ISSN-L)
- 1520-5029
- OpenAlex
- W2094991496
- Cited by
- 236
- References
- 0
- FWCI
- 0.67
- Type
- journal article
- Language
- en
- Open access
- closed
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- Samolada, M. C., Papafotica, A., & Vasalos, I. A. (2000). Catalyst Evaluation for Catalytic Biomass Pyrolysis. Energy & Fuels. https://doi.org/10.1021/ef000026b
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