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Cited by 254

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Catalytic Conversion of Guaiacol Catalyzed by Platinum Supported on Alumina: Reaction Network Including Hydrodeoxygenation Reactions

Nimmanwudipong, Tarit, Runnebaum, Ron C., Block, David E., Gates, Bruce C.·2011·Energy & Fuels

Abstract

The conversion of guaiacol catalyzed by Pt/γ-Al 2 O 3 in the presence of H 2 was investigated with a flow reactor at 573 K and 140 kPa. Dozens of reaction products were identified, with the most abundant being phenol, catechol, and 3-methylcatechol. The kinetically significant reaction classes were found to be hydrogenolysis [including hydrodeoxygenation (HDO)], hydrogenation, and transalkylation. Selectivity–conversion data were used to determine an approximate quantitative reaction network accounting for the primary products, and a more detailed qualitative network was also inferred. Catalytic HDO was evidenced by the production of anisole and phenol. The HDO selectivity increased with an increasing H 2 partial pressure and a decreasing temperature. Products formed by transalkylation reactions match those produced in the conversion catalyzed by HY zeolite, in which no deoxygenated products were observed.

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Metadata

Authors
Nimmanwudipong, T., Runnebaum, R. C., Block, D. E., & Gates, B. C.
Venue
Energy & Fuels
Published
2011-07-25
Volume
25
Issue
8
Pages
3417-3427
ISSN
  • 0887-0624 (ISSN-L)
  • 1520-5029
OpenAlex
W2328531464
Cited by
254
References
3
FWCI
10.21
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Catalytic Conversion of Guaiacol Catalyzed by Platinum Supported on Alumina: Reaction Network Including Hydrodeoxygenation Reactions. https://app.cochat.ai/papers/10.1021/ef200803d
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Nimmanwudipong, T., Runnebaum, R. C., Block, D. E., & Gates, B. C. (2011). Catalytic Conversion of Guaiacol Catalyzed by Platinum Supported on Alumina: Reaction Network Including Hydrodeoxygenation Reactions. Energy & Fuels. https://doi.org/10.1021/ef200803d

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