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Temporal and Spatial Studies of Autocatalyst-Derived Platinum, Rhodium, and Palladium and Selected Vehicle-Derived Trace Elements in the Environment
Abstract
The distribution of platinum, rhodium, and palladium (platinum-group elements; PGEs) adjacent to two major U.K. roads shows a rapid decrease (more than 1 order of magnitude) away from the road and reflects patterns shown by other traffic-derived trace elements such as Pb and Zn. However, ratios of Pt:Rh remain relatively constant from 0 to 10 m distance, suggesting that at least some of the PGEs are transported away from the source. A temporal study over a 12-month period, of road dust and surface samples, reveals elevated concentrations above background levels, with maximum values of Pt >500 ng g(-1), Rh 70 ng g(-1), and Pd 70 ng g(-1). Concentrations vary considerably throughout the year and show some tentative correlation with rainfall. Element speciation, an essential control on mobility and hence distribution, was investigated, and the results of solubility experiments show that up to 30% of the Pd present dissolves in acid solutions. This indicates that at least some of the Pd is present in a soluble form and is therefore potentially highly mobile.
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“For example, platinum, rhodium and palladium lost from automotive catalytic converters accumulate preferentially in soils adjacent to highways ( 59 ).”
From The Anthropocene is functionally and stratigraphically distinct from the Holocene (2016) · cites this paper as [59]
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Metadata
- Authors
- Jarvis, K. E., Parry, S. J., & Piper, J. M.
- Affiliations
- Kingston University London (GB)
- Imperial College London (GB)
- Corresponding author
- Jarvis, Kym E.
- Parry, Susan J.
- Venue
- Environmental Science & Technology
- Publisher
- American Chemical Society (ACS)
- Published
- 2001-02-10
- Volume
- 35
- Issue
- 6
- Pages
- 1031-1036
- ISSN
- 0013-936X (ISSN-L)
- 1520-5851
- OpenAlex
- W1990297533
- Cited by
- 228
- References
- 22
- Citations by year
- 2025: 3 · 2024: 1 · 2023: 9 · 2022: 5 · 2021: 3 · 2020: 8 · 2019: 5 · 2018: 6 · 2017: 9 · 2016: 7 · 2015: 8 · 2014: 15 · 2013: 6 · 2012: 10
- FWCI
- 20.94
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Environmental Science & Technology (publishedVersion)
- PubMed (publishedVersion)
- Research Repository (Kingston University London) (submittedVersion)
- Funders
- Natural Environment Research Council
- Topics
- Physical Sciences › Environmental Science › Pollution › Heavy metals in environment
- Physical Sciences › Environmental Science › Pollution › Pharmaceutical and Antibiotic Environmental Impacts
- Physical Sciences › Environmental Science › Water Science and Technology › Environmental and Analytical Chemistry Studies
- Keywords
- platinum group elements, platinum, rhodium, palladium, road traffic emissions, road dust, spatial distribution, temporal variation, element speciation, acid solubility, element mobility, lead, zinc, rainfall
- MeSH terms
- Air Pollution, Vehicle Emissions, Environmental Monitoring, Lead, Palladium, Platinum, Rain, Rhodium, Seasons, Solubility
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
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