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Transport of nonpolar organic compounds from surface water to groundwater. Laboratory sorption studies

Schwarzenbach, Rene P., Westall, John.·1981·Environmental Science & Technology

Abstract

Laboratory batch and column experiments have been conducted to elucidate the sorption behavior of nonpolar organic compounds (e.g., halogenated alkenes and benzenes) in a river water-groundwater infiltration system. For the low concentrations typical of the environment, sorption equilibria can be described by the equation S = KpC, where S = concentration in the solid phase, Kp = partition coefficient, and C = concentration in the liquid phase. For a variety of sorbents, it was found that the partition coefficient KpZ of a particular compound Z can be estimated from its 1-octanol/water partition coefficient KOWZ and from the organic-carbon (OC) content fOC (fraction organic carbon) of the sorbents if fOC is greater than 0.001: log KpZ = 0.72 log KOWZ + log fOC(s) + 0.49. Sorption was found to be reversible, but sorption kinetics may have an effect on material transport over the range of flow velocities encountered in aquifers. The conclusions of this study are applicable to a wide range of sorption and transport problems including artificial groundwater recharge and leaching of pollutants from landfills.

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Metadata

Authors
Schwarzenbach, R. P., & Westall, J.
Venue
Environmental Science & Technology
Published
1981-11-01
Volume
15
Issue
11
Pages
1360-1367
ISSN
  • 0013-936X (ISSN-L)
  • 1520-5851
OpenAlex
W2069032765
Cited by
889
References
0
FWCI
20.66
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Transport of nonpolar organic compounds from surface water to groundwater. Laboratory sorption studies. https://app.cochat.ai/papers/10.1021/es00093a009
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Schwarzenbach, R. P., & Westall, J. (1981). Transport of nonpolar organic compounds from surface water to groundwater. Laboratory sorption studies. Environmental Science & Technology. https://doi.org/10.1021/es00093a009

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