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Transport of nonpolar organic compounds from surface water to groundwater. Laboratory sorption studies
Abstract
Laboratory batch and column experiments have been conducted to elucidate the sorption behavior of nonpolar organic compounds (e.g., halogenated alkenes and benzenes) in a river water-groundwater infiltration system. For the low concentrations typical of the environment, sorption equilibria can be described by the equation S = KpC, where S = concentration in the solid phase, Kp = partition coefficient, and C = concentration in the liquid phase. For a variety of sorbents, it was found that the partition coefficient KpZ of a particular compound Z can be estimated from its 1-octanol/water partition coefficient KOWZ and from the organic-carbon (OC) content fOC (fraction organic carbon) of the sorbents if fOC is greater than 0.001: log KpZ = 0.72 log KOWZ + log fOC(s) + 0.49. Sorption was found to be reversible, but sorption kinetics may have an effect on material transport over the range of flow velocities encountered in aquifers. The conclusions of this study are applicable to a wide range of sorption and transport problems including artificial groundwater recharge and leaching of pollutants from landfills.
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Cited by
Biogeochemistry of landfill leachate plumes
Christensen, T. H., Kjeldsen, P., Bjerg, P. L., Jensen, D. L., Christensen, J. B., Baun, A., Albrechtsen, H.-J., & Heron, G. (2001) · Applied Geochemistry · doi:10.1016/s0883-2927(00)00082-2 · Cited by 1,382
Ecotoxicology of Organotin Compounds
Fent, K. (1996) · Critical Reviews in Toxicology · doi:10.3109/10408449609089891 · Cited by 992
Competitive Sorption between Atrazine and Other Organic Compounds in Soils and Model Sorbents
Xing, B., Pignatello, J. J., & Gigliotti, B. (1996) · Environmental Science & Technology · doi:10.1021/es950350z · Cited by 538
Huang, W., Peng, P., Yu, Z., & Fu, J. (2003) · Applied Geochemistry · doi:10.1016/s0883-2927(02)00205-6 · Cited by 435
Huang, W., & Weber, W. J. (1997) · Environmental Science & Technology · doi:10.1021/es960995e · Cited by 414
Metadata
- Authors
- Schwarzenbach, R. P., & Westall, J.
- Venue
- Environmental Science & Technology
- Publisher
- American Chemical Society (ACS)
- Published
- 1981-11-01
- Volume
- 15
- Issue
- 11
- Pages
- 1360-1367
- ISSN
- 0013-936X (ISSN-L)
- 1520-5851
- OpenAlex
- W2069032765
- Cited by
- 889
- References
- 0
- FWCI
- 20.66
- Type
- journal article
- Language
- en
- Open access
- closed
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- Schwarzenbach, R. P., & Westall, J. (1981). Transport of nonpolar organic compounds from surface water to groundwater. Laboratory sorption studies. Environmental Science & Technology. https://doi.org/10.1021/es00093a009
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