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Reduction of Haloacetic Acids by Fe0: Implications for Treatment and Fate

Hozalski, Raymond M., Zhang, Li, Arnold, William A.·2001·Environmental Science & Technology
DOI 10.1021/es001785b
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Abstract

To predict the fate of haloacetic acids (HAAs) in natural or engineered systems, information is needed concerning the types of reactions that these compounds undergo, the rates of those reactions, and the products that are formed. Given that many drinking water distribution systems consist of unlined cast iron pipe, reactions of HAAs with elemental iron (Fe0) may play a role in determining the fate of HAAs in these systems. In addition, zerovalent iron may prove to be an effective treatment technology for the removal of HAAs from chlorinated drinking water and wastewater. Thus, batch experiments were used to investigate reactions of four trihaloacetic acids, trichloroacetic acid (TCAA), tribromoacetic acid (TBAA), chlorodibromoacetic acid (CDBAA), and bromodichloroacetic acid (BDCAA), with Fe0. All compounds readily reacted with Fe0, and investigation of product formation and subsequent disappearance revealed that the reactions proceeded via sequential hydrogenolysis. Bromine was preferentially removed over chlorine, and TBAA was the only compound completely dehalogenated to acetic acid. In compounds containing chlorine, the final product of reactions with Fe0 was monochloroacetic acid. Halogen mass balances were 95-112%, and carbon mass balances were 62.6-112%. The pseudo-first-order rate constants for trihaloacetic acid degradation were as follows: BDCAA (10.6 +/- 3.1 h-1) > CDBAA (1.43 +/- 0.32 h-1) approximately TBAA (1.41 +/- 0.28 h-1) >> TCAA (0.08 +/- 0.02 h-1).

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Metadata

Authors
Hozalski, R. M., Zhang, L., & Arnold, W. A.
Affiliations
University of Minnesota (US)
ORCID
Venue
Environmental Science & Technology
Publisher
American Chemical Society (ACS)
Published
2001-04-27
Volume
35
Issue
11
Pages
2258-2263
ISSN
  • 0013-936X (ISSN-L)
  • 1520-5851
DOI
10.1021/es001785b
OpenAlex
W2053783788
Cited by
113
References
0
Citations by year
2025: 1 · 2024: 6 · 2023: 3 · 2022: 2 · 2021: 7 · 2020: 4 · 2019: 3 · 2018: 7 · 2017: 7 · 2016: 8 · 2015: 4 · 2014: 8 · 2013: 6 · 2012: 6
FWCI
2.66
Type
journal article
Language
en
Open access
closed
Locations
  • Environmental Science & Technology (publishedVersion)
  • PubMed (publishedVersion)
Funders
  • U.S. Environmental Protection Agency
  • Water Research Foundation
  • American Water Works Association Research Foundation
Topics
  • Physical Sciences › Environmental Science › Health, Toxicology and Mutagenesis › Water Treatment and Disinfection
  • Physical Sciences › Environmental Science › Environmental Engineering › Environmental remediation with nanomaterials
  • Physical Sciences › Environmental Science › Water Science and Technology › Advanced oxidation water treatment
Keywords
haloacetic acids, trihaloacetic acids, zero-valent iron, hydrogenolysis, dehalogenation, bromine removal, dechlorination, trichloroacetic acid, tribromoacetic acid, drinking water distribution systems, cast iron pipes, wastewater treatment, degradation kinetics, mass balance
MeSH terms
Bromine, Chlorine, Halogens, Hydrogen, Iron, Models, Theoretical, Oxidation-Reduction, Water Pollutants, Chemical, Water Supply, Acetic Acid

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