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High-Performance Ti/BDD Electrodes for Pollutant Oxidation
Abstract
Deposition of stable boron-doped diamond (BDD) films on Ti substrates is believed to be very difficult. In the present study, the stability of Ti/BDD electrodes has been significantly improved by using an organic additive, CH2(OCH3)2. The improved electrodes had service lives of 175-264 h under accelerated life test conditions, which are 2.3-3.0 times longer than the service lives of electrodes prepared with the conventional H2 + CH4 mixture. Raman spectroscopy, X-ray diffraction (XRD), and scanning electron microscopy (SEM) examinations demonstrated thatthe films had well-defined diamond features. The current efficiency (CE) obtained on Ti/BDD was 46.9-78.5% in oxidizing acetic acid, maleic acid, phenol, and dyes, which is 1.6-4.3-fold higher than that obtained on the typical Ti/ Sb2O5-SnO2 electrode. We used a Ti/BDD electrode prepared with H2 + CH4 + CH2(OCH3)2 for over 300 h; its activity remained superior. The successful development of stable and active Ti/BDD electrodes significantly increases the feasibility of industrial applications of anodic oxidation in wastewater treatment.
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Citations
Cited by
Direct And Mediated Anodic Oxidation of Organic Pollutants
Panizza, M., & Cerisola, G. (2009) · Chemical Reviews · doi:10.1021/cr9001319 · Cited by 2,346
Brillas, E., & Martínez-Huitle, C. A. (2015) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2014.11.016 · Cited by 2,009
Martínez-Huitle, C. A., & Ferro, S. (2006) · Chem. Soc. Rev. · doi:10.1039/b517632h · Cited by 1,840
Application of diamond electrodes to electrochemical processes
Panizza, M., & Cerisola, G. (2005) · Electrochimica Acta · doi:10.1016/j.electacta.2005.04.023 · Cited by 773
Degradation of perfluorinated compounds on a boron-doped diamond electrode
Zhuo, Q., Deng, S., Yang, B., Huang, J., Wang, B., Zhang, T., & Yu, G. (2012) · Electrochimica Acta · doi:10.1016/j.electacta.2012.04.145 · Cited by 262
Metadata
- Authors
- Chen, X., Chen, G., Gao, F., & Yue, P. L.
- Venue
- Environmental Science & Technology
- Publisher
- American Chemical Society (ACS)
- Published
- 2003-09-27
- Volume
- 37
- Issue
- 21
- Pages
- 5021-5026
- ISSN
- 0013-936X (ISSN-L)
- 1520-5851
- OpenAlex
- W2080790911
- Cited by
- 182
- References
- 0
- FWCI
- 7.44
- Type
- journal article
- Language
- en
- Open access
- closed
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