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Secondary Organic Aerosol Production from Terpene Ozonolysis. 2. Effect of NOx Concentration

Presto, Albert A., Huff Hartz, Kara E., Donahue, Neil M.·2005·Environmental Science & Technology

Abstract

We report secondary organic aerosol (SOA) yields from the ozonolysis of alpha-pinene in the presence of NO and NO2. Experimental conditions are characterized by the [VOC]0/ [NOx]0 ratio (ppbC/ppb), which varies from approximately 1 to approximately 300. SOA yield is constant for [VOC]0/[NOx]0 > approximately 15 and decreases dramatically (by more than a factor of 4) as [VOC]0/[NOx]0 decreases. Aerosol production is completely suppressed in the presence of NO for [VOC]0/[NOx]0 < or = 4.5. Fouriertransform IR analysis of filter samples reveals that nitrate-containing species contribute significantly to the total aerosol mass at low [VOC]0/[NOx]0. Yield reduction is a result of the formation of a more volatile product distribution as [VOC]0/[NOx]0 decreases; we propose that the change in the product distribution is driven by changes in the gas-phase chemistry as NOx concentration increases. We also present two-product model parameters to describe aerosol production from the alpha-pinene/0/NOx system under both high- and low-NOx conditions.

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Metadata

Authors
Presto, A. A., Huff Hartz, K. E., & Donahue, N. M.
Venue
Environmental Science & Technology
Published
2005-08-16
Volume
39
Issue
18
Pages
7046-7054
ISSN
  • 0013-936X (ISSN-L)
  • 1520-5851
OpenAlex
W2332831387
Cited by
282
References
0
FWCI
9.38
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Secondary Organic Aerosol Production from Terpene Ozonolysis. 2. Effect of NOx Concentration. https://app.cochat.ai/papers/10.1021/es050400s
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Presto, A. A., Huff Hartz, K. E., & Donahue, N. M. (2005). Secondary Organic Aerosol Production from Terpene Ozonolysis. 2. Effect of NOx Concentration. Environmental Science & Technology. https://doi.org/10.1021/es050400s

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