The DOI matches its Crossref record; 22 of the 22 references it cites were found in a registry or an index.
Kinetics of the Oxidation of Phenols and Phenolic Endocrine Disruptors during Water Treatment with Ferrate (Fe(VI))
Open accessAbstract
The ability of ferrate (Fe(VI)) to oxidize phenolic endocrine-disrupting chemicals (EDCs) and phenols during water treatment was examined by determining the apparent second-order rate constants (k(app0) for the reaction of Fe(VI) with selected environmentally relevant phenolic EDCs (17alpha-ethinylestradiol, beta-estradiol, and bisphenol A) and 10 substituted phenols at pH values ranging from 6 to 11. The three selected groups of EDCs showed appreciable reactivity with Fe(VI) (kapp at pH 7 ranged from 6.4 x 102 to 7.7 x 10(2) M(-1) s(-1)). The k(app) for the substituted phenols studied at pH 7 ranged from 6.6 to 3.6 x 10(3) M(-1) s(-1), indicating that many other potential phenolic EDCs can be oxidized by Fe(VI) during water treatment. The Hammett-type correlations were determined for the reaction between HFeO4- and the undissociated (log(k) = 2.24-2.27sigma+) and dissociated phenol (log(k) = 4.33-3.60sigma+). A comparison of the Hammett correlation obtained for the reaction between HFeO4- and dissociated phenol with those obtained from other drinking water oxidants revealed that HFeO4- is a relatively mild oxidant of phenolic compounds. The effectiveness of Fe(VI) for the oxidative removal of phenolic EDCs was also confirmed in both natural water and wastewater.
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Metadata
- Authors
- Lee, Y., Yoon, J., & von Gunten, U.
- Venue
- Environmental Science & Technology
- Publisher
- American Chemical Society (ACS)
- Published
- 2005-10-18
- Volume
- 39
- Issue
- 22
- Pages
- 8978-8984
- ISSN
- 0013-936X (ISSN-L)
- 1520-5851
- OpenAlex
- W1984182687
- Cited by
- 292
- References
- 22
- FWCI
- 8.69
- Type
- journal article
- Language
- en
- Open access
- green
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