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Sources and Sinks of Hydroxyl Radicals upon Irradiation of Natural Water Samples
Abstract
Hydroxyl radical formation rates, steady-state concentration, and overall scavenging rate constant were measured by irradiation of surface lake water samples from Piedmont (NW Italy) and nitrate-rich groundwater samples from Moldova (NE Romania). Dissolved organic matter (DOM) was the main source and sink of *OH upon lake water irradiation, with [*OH] being independent of DOM amount. Water oxidation by photoexcited DOM is a likely *OH source in the presence of very low levels of nitrate and dissolved iron. Under different circumstances it is not possible to exclude other processes, e.g., DOM-enhanced photo-Fenton reactions. Under the hypotheses of no interaction and absence of mutual screening of radiation, nitrate would prevail over DOM as *OH source for a NO3-/DOM ratio higher than 3.3 x 10(-5) (mol NO3-) (mg C)(-1), DOM prevailing for lower values. Substantial DOM photolability was observed upon irradiation of nitrate-rich groundwater, mainly due to the elevated *OH generation rate. For the first time to our knowledge, evidence was also obtained of the photoformation of potentially toxic and/or mutagenic nitroaromatic compounds upon irradiation of natural lake water and groundwater samples, proportionally to the nitrate levels.
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Buxton, G. V., Greenstock, C. L., Helman, W. P., & Ross, A. B. (1988) · Journal of Physical and Chemical Reference Data · doi:10.1063/1.555805 · Cited by 12,332
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Ji, Y., Fan, Y., Liu, K., Kong, D., & Lu, J. (2015) · Water Research · doi:10.1016/j.watres.2015.09.005 · Cited by 439
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Self-citationWols, B. A., Harmsen, D. J. H., Wanders-Dijk, J., Beerendonk, E. F., & Hofman-Caris, C. H. M. (2015) · Water Research · doi:10.1016/j.watres.2015.02.014 · Cited by 92
Metadata
- Authors
- Vione, D., Falletti, G., Maurino, V., Minero, C., Pelizzetti, E., Malandrino, M., Ajassa, R., Olariu, R.-I., & Arsene, C.
- Venue
- Environmental Science & Technology
- Publisher
- American Chemical Society (ACS)
- Published
- 2006-05-10
- Volume
- 40
- Issue
- 12
- Pages
- 3775-3781
- ISSN
- 0013-936X (ISSN-L)
- 1520-5851
- OpenAlex
- W2041269463
- Cited by
- 403
- References
- 1
- FWCI
- 15.93
- Type
- journal article
- Language
- en
- Open access
- closed
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- Vione, D., Falletti, G., Maurino, V., Minero, C., Pelizzetti, E., Malandrino, M., Ajassa, R., Olariu, R.-I., & Arsene, C. (2006). Sources and Sinks of Hydroxyl Radicals upon Irradiation of Natural Water Samples. Environmental Science & Technology. https://doi.org/10.1021/es052206b
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