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Source Attribution of Submicron Organic Aerosols during Wintertime Inversions by Advanced Factor Analysis of Aerosol Mass Spectra
Abstract
Real-time measurements of submicrometer aerosol were performed using an Aerodyne aerosol mass spectrometer (AMS) during three weeks at an urban background site in Zurich (Switzerland) in January 2006. A hybrid receptor model which incorporates a priori known source composition was applied to the AMS highly time-resolved organic aerosol mass spectra. Three sources and components of submicrometer organic aerosols were identified: the major component was oxygenated organic aerosol (OOA), mostly representing secondary organic aerosol and accounting on average for 52-57% of the particulate organic mass. Radiocarbon (14C) measurements of organic carbon (OC) indicated that approximately 31 and approximately 69% of OOA originated from fossil and nonfossil sources, respectively. OOA estimates were strongly correlated with measured particulate ammonium. Particles from wood combustion (35-40%) and 3-13% traffic-related hydrocarbon-like organic aerosol (HOA) accounted for the other half of measured organic matter (OM). Emission ratios of modeled HOA to measured nitrogen oxides (NOx) and OM from wood burning to levoglucosan from filter analyses were found to be consistent with literature values.
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Cited by
Ulbrich, I. M., Canagaratna, M. R., Zhang, Q., Worsnop, D. R., & Jimenez, J. L. (2009) · Atmospheric Chemistry and Physics · doi:10.5194/acp-9-2891-2009 · Cited by 1,534
A review of Secondary Organic Aerosol (SOA) formation from isoprene
Carlton, A. G., Wiedinmyer, C., & Kroll, J. H. (2009) · Atmospheric Chemistry and Physics · doi:10.5194/acp-9-4987-2009 · Cited by 912
Brown, S. G., Eberly, S., Paatero, P., & Norris, G. A. (2015) · Science of The Total Environment · doi:10.1016/j.scitotenv.2015.01.022 · Cited by 733
The Molecular Identification of Organic Compounds in the Atmosphere: State of the Art and Challenges
Nozière, B., Kalberer, M., Claeys, M., Allan, J., D’Anna, B., Decesari, S., Finessi, E., Glasius, M., Grgić, I., Hamilton, J. F., et al. (2015) · Chemical Reviews · doi:10.1021/cr5003485 · Cited by 656
Self-citationCanonaco, F., Crippa, M., Slowik, J. G., Baltensperger, U., & Prévôt, A. S. H. (2013) · Atmospheric Measurement Techniques · doi:10.5194/amt-6-3649-2013 · Cited by 630
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Metadata
- Authors
- Lanz, V. A., Alfarra, M. R., Baltensperger, U., Buchmann, B., Hueglin, C., Szidat, S., Wehrli, M. N., Wacker, L., Weimer, S., Caseiro, A., Puxbaum, H., & Prevot, A. S. H.
- Venue
- Environmental Science & Technology
- Publisher
- American Chemical Society (ACS)
- Published
- 2007-11-21
- Volume
- 42
- Issue
- 1
- Pages
- 214-220
- ISSN
- 0013-936X (ISSN-L)
- 1520-5851
- OpenAlex
- W2022130129
- Cited by
- 273
- References
- 0
- FWCI
- 14.44
- Type
- journal article
- Language
- en
- Open access
- closed
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- Lanz, V. A., Alfarra, M. R., Baltensperger, U., Buchmann, B., Hueglin, C., Szidat, S., Wehrli, M. N., Wacker, L., Weimer, S., Caseiro, A., Puxbaum, H., & Prevot, A. S. H. (2008). Source Attribution of Submicron Organic Aerosols during Wintertime Inversions by Advanced Factor Analysis of Aerosol Mass Spectra. Environmental Science & Technology. https://doi.org/10.1021/es0707207
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