The DOI matches its Crossref record; 18 of the 18 references it cites were found in a registry or an index.
Isoprene Epoxydiols as Precursors to Secondary Organic Aerosol Formation: Acid-Catalyzed Reactive Uptake Studies with Authentic Compounds
Open accessAbstract
Isoprene epoxydiols (IEPOX), formed from the photooxidation of isoprene under low-NO(x) conditions, have recently been proposed as precursors of secondary organic aerosol (SOA) on the basis of mass spectrometric evidence. In the present study, IEPOX isomers were synthesized in high purity (>99%) to investigate their potential to form SOA via reactive uptake in a series of controlled dark chamber studies followed by reaction product analyses. IEPOX-derived SOA was substantially observed only in the presence of acidic aerosols, with conservative lower-bound yields of 4.7-6.4% for β-IEPOX and 3.4-5.5% for δ-IEPOX, providing direct evidence for IEPOX isomers as precursors to isoprene SOA. These chamber studies demonstrate that IEPOX uptake explains the formation of known isoprene SOA tracers found in ambient aerosols, including 2-methyltetrols, C(5)-alkene triols, dimers, and IEPOX-derived organosulfates. Additionally, we show reactive uptake on the acidified sulfate aerosols supports a previously unreported acid-catalyzed intramolecular rearrangement of IEPOX to cis- and trans-3-methyltetrahydrofuran-3,4-diols (3-MeTHF-3,4-diols) in the particle phase. Analysis of these novel tracer compounds by aerosol mass spectrometry (AMS) suggests that they contribute to a unique factor resolved from positive matrix factorization (PMF) of AMS organic aerosol spectra collected from low-NO(x), isoprene-dominated regions influenced by the presence of acidic aerosols.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Guenther, A., Karl, T., Harley, P., Wiedinmyer, C., Palmer, P. I., & Geron, C. (2006) · Atmospheric Chemistry and Physics · doi:10.5194/acp-6-3181-2006 · Cited by 4,603
The formation, properties and impact of secondary organic aerosol: current and emerging issues
Hallquist, M., Wenger, J. C., Baltensperger, U., Rudich, Y., Simpson, D., Claeys, M., Dommen, J., Donahue, N. M., George, C., Goldstein, A. H., et al. (2009) · Atmospheric Chemistry and Physics · doi:10.5194/acp-9-5155-2009 · Cited by 4,031
Self-citationField-Deployable, High-Resolution, Time-of-Flight Aerosol Mass Spectrometer
DeCarlo, P. F., Kimmel, J. R., Trimborn, A., Northway, M. J., Jayne, J. T., Aiken, A. C., Gonin, M., Fuhrer, K., Horvath, T., Docherty, K. S., et al. (2006) · Analytical Chemistry · doi:10.1021/ac061249n · Cited by 2,149
Self-citationGas/Particle Partitioning and Secondary Organic Aerosol Yields
Odum, J. R., Hoffmann, T., Bowman, F., Collins, D., Flagan, R. C., & Seinfeld, J. H. (1996) · Environmental Science & Technology · doi:10.1021/es950943+ · Cited by 1,529
Formation of Secondary Organic Aerosols Through Photooxidation of Isoprene
Claeys, M., Graham, B., Vas, G., Wang, W., Vermeylen, R., Pashynska, V., Cafmeyer, J., Guyon, P., Andreae, M. O., Artaxo, P., et al. (2004) · Science · doi:10.1126/science.1092805 · Cited by 1,501
Reactive intermediates revealed in secondary organic aerosol formation from isoprene
Surratt, J. D., Chan, A. W. H., Eddingsaas, N. C., Chan, M., Loza, C. L., Kwan, A. J., Hersey, S. P., Flagan, R. C., Wennberg, P. O., & Seinfeld, J. H. (2010) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.0911114107 · Cited by 1,081
Self-citationA review of Secondary Organic Aerosol (SOA) formation from isoprene
Carlton, A. G., Wiedinmyer, C., & Kroll, J. H. (2009) · Atmospheric Chemistry and Physics · doi:10.5194/acp-9-4987-2009 · Cited by 912
Unexpected Epoxide Formation in the Gas-Phase Photooxidation of Isoprene
Paulot, F., Crounse, J. D., Kjaergaard, H. G., Kürten, A., St. Clair, J. M., Seinfeld, J. H., & Wennberg, P. O. (2009) · Science · doi:10.1126/science.1172910 · Cited by 903
Secondary Organic Aerosol Formation from Isoprene Photooxidation
Kroll, J. H., Ng, N. L., Murphy, S. M., Flagan, R. C., & Seinfeld, J. H. (2006) · Environmental Science & Technology · doi:10.1021/es0524301 · Cited by 782
Chemical Composition of Secondary Organic Aerosol Formed from the Photooxidation of Isoprene
Surratt, J. D., Murphy, S. M., Kroll, J. H., Ng, N. L., Hildebrandt, L., Sorooshian, A., Szmigielski, R., Vermeylen, R., Maenhaut, W., Claeys, M., et al. (2006) · The Journal of Physical Chemistry A · doi:10.1021/jp061734m · Cited by 661
Self-citationThe Southeastern Aerosol Research and Characterization Study: Part 1—Overview
Hansen, D. A., Edgerton, E. S., Hartsell, B. E., Jansen, J. J., Kandasamy, N., Hidy, G. M., & Blanchard, C. L. (2003) · Journal of the Air & Waste Management Association · doi:10.1080/10473289.2003.10466318 · Cited by 275
Self-citationChan, M. N., Surratt, J. D., Claeys, M., Edgerton, E. S., Tanner, R. L., Shaw, S. L., Zheng, M., Knipping, E. M., Eddingsaas, N. C., Wennberg, P. O., et al. (2010) · Environmental Science & Technology · doi:10.1021/es100596b · Cited by 161
Self-citationRobinson, N., Hamilton, J. F., Allan, J. D., Langford, B., Oram, D. E., Chen, Q., Docherty, K. S., Farmer, D. K., Jimenez, J. L., Ward, M. W., et al. (2011) · Atmospheric chemistry and physics · doi:10.5194/acp-11-1039-2011 · Cited by 153
Self-citationMinerath, E. C., & Elrod, M. J. (2009) · Environmental Science & Technology · doi:10.1021/es8029076 · Cited by 124
Kinetics of the Hydrolysis of Atmospherically Relevant Isoprene-Derived Hydroxy Epoxides
Cole-Filipiak, N. C., O’Connor, A. E., & Elrod, M. J. (2010) · Environmental Science & Technology · doi:10.1021/es1019228 · Cited by 78
Kinetics of the Reactions of Isoprene-Derived Epoxides in Model Tropospheric Aerosol Solutions
Minerath, E. C., Schultz, M. P., & Elrod, M. J. (2009) · Environmental Science & Technology · doi:10.1021/es902304p · Cited by 74
Slowik, J. G., Brook, J. R., Chang, R., Evans, G. J., Hayden, K. L., Jeong, C., Li, S., Liggio, J., Liu, P. S. K., McGuire, M., et al. (2011) · Atmospheric chemistry and physics · doi:10.5194/acp-11-2991-2011 · Cited by 74
Yamaguchi, A., Hiyoshi, N., Sato, O., Bando, K. K., & Shirai, M. (2008) · Green Chemistry · doi:10.1039/b812318g · Cited by 71
Cited by
Formation of Urban Fine Particulate Matter
Zhang, R., Wang, G., Guo, S., Zamora, M. L., Ying, Q., Lin, Y., Wang, W., Hu, M., & Wang, Y. (2015) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00067 · Cited by 1,426
Self-citationCanagaratna, M. R., Jimenez, J. L., Kroll, J. H., Chen, Q., Kessler, S. H., Massoli, P., Hildebrandt Ruiz, L., Fortner, E., Williams, L. R., Wilson, K. R., et al. (2015) · Atmospheric Chemistry and Physics · doi:10.5194/acp-15-253-2015 · Cited by 1,013
Self-citationPöschl, U., & Shiraiwa, M. (2015) · Chemical Reviews · doi:10.1021/cr500487s · Cited by 657
The Molecular Identification of Organic Compounds in the Atmosphere: State of the Art and Challenges
Nozière, B., Kalberer, M., Claeys, M., Allan, J., D’Anna, B., Decesari, S., Finessi, E., Glasius, M., Grgić, I., Hamilton, J. F., et al. (2015) · Chemical Reviews · doi:10.1021/cr5003485 · Cited by 656
Self-citationThe MCM v3.3.1 degradation scheme for isoprene
Jenkin, M. E., Young, J. C., & Rickard, A. R. (2015) · Atmospheric Chemistry and Physics · doi:10.5194/acp-15-11433-2015 · Cited by 623
Metadata
- Authors
- Lin, Y.-H., Zhang, Z., Docherty, K. S., Zhang, H., Budisulistiorini, S. H., Rubitschun, C. L., Shaw, S. L., Knipping, E. M., Edgerton, E. S., Kleindienst, T. E., Gold, A., & Surratt, J. D.
- Venue
- Environmental Science & Technology
- Publisher
- American Chemical Society (ACS)
- Published
- 2011-12-13
- Volume
- 46
- Issue
- 1
- Pages
- 250-258
- ISSN
- 0013-936X (ISSN-L)
- 1520-5851
- OpenAlex
- W2048640559
- Cited by
- 398
- References
- 18
- FWCI
- 13.91
- Type
- journal article
- Language
- en
- Open access
- green
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
