The DOI matches its Crossref record; 36 of the 36 references it cites were found in a registry or an index.
Secondary Organic Aerosol Formation and Organic Nitrate Yield from NO3Oxidation of Biogenic Hydrocarbons
Open accessAbstract
The secondary organic aerosol (SOA) mass yields from NO3 oxidation of a series of biogenic volatile organic compounds (BVOCs), consisting of five monoterpenes and one sesquiterpene (α-pinene, β-pinene, Δ-3-carene, limonene, sabinene, and β-caryophyllene), were investigated in a series of continuous flow experiments in a 10 m(3) indoor Teflon chamber. By making in situ measurements of the nitrate radical and employing a kinetics box model, we generate time-dependent yield curves as a function of reacted BVOC. SOA yields varied dramatically among the different BVOCs, from zero for α-pinene to 38-65% for Δ-3-carene and 86% for β-caryophyllene at mass loading of 10 μg m(-3), suggesting that model mechanisms that treat all NO3 + monoterpene reactions equally will lead to errors in predicted SOA depending on each location's mix of BVOC emissions. In most cases, organonitrate is a dominant component of the aerosol produced, but in the case of α-pinene, little organonitrate and no aerosol is formed.
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Cites
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A large source of low-volatility secondary organic aerosol
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Cited by
Lee, B. H., Mohr, C., Lopez-Hilfiker, F. D., Lutz, A., Hallquist, M., Lee, L., Romer, P., Cohen, R. C., Iyer, S., Kurtén, T., et al. (2016) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1508108113 · Cited by 389
Self-citationSchwantes, R. H., Emmons, L. K., Orlando, J. J., Barth, M. C., Tyndall, G. S., Hall, S. R., Ullmann, K., St. Clair, J. M., Blake, D. R., Wisthaler, A., et al. (2020) · Atmospheric Chemistry and Physics · doi:10.5194/acp-20-3739-2020 · Cited by 112
Metadata
- Authors
- Fry, J. L., Draper, D. C., Barsanti, K. C., Smith, J. N., Ortega, J., Winkler, P. M., Lawler, M. J., Brown, S. S., Edwards, P. M., Cohen, R. C., & Lee, L.
- Venue
- Environmental Science & Technology
- Publisher
- American Chemical Society (ACS)
- Published
- 2014-10-08
- Volume
- 48
- Issue
- 20
- Pages
- 11944-11953
- ISSN
- 0013-936X (ISSN-L)
- 1520-5851
- OpenAlex
- W2046884997
- Cited by
- 262
- References
- 36
- FWCI
- 11.47
- Type
- journal article
- Language
- en
- Open access
- hybrid
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- Fry, J. L., Draper, D. C., Barsanti, K. C., Smith, J. N., Ortega, J., Winkler, P. M., Lawler, M. J., Brown, S. S., Edwards, P. M., Cohen, R. C., & Lee, L. (2014). Secondary Organic Aerosol Formation and Organic Nitrate Yield from NO3Oxidation of Biogenic Hydrocarbons. Environmental Science & Technology. https://doi.org/10.1021/es502204x
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