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New Application of Z-Scheme Ag3PO4/g-C3N4Composite in Converting CO2to Fuel

He, Yiming, Zhang, Lihong, Teng, Botao, Fan, Maohong·2015·Environmental Science & Technology

Abstract

This research was designed for the first time to investigate the activities of photocatalytic composite, Ag3PO4/g-C3N4, in converting CO2 to fuels under simulated sunlight irradiation. The composite was synthesized using a simple in situ deposition method and characterized by various techniques including Brunauer-Emmett-Teller method (BET), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), UV-vis diffuse reflectance spectroscopy (DRS), photoluminescence spectroscopy (PL), and an electrochemical method. Thorough investigation indicated that the composite consisted of Ag3PO4, Ag, and g-C3N4. The introduction of Ag3PO4 on g-C3N4 promoted its light absorption performance. However, more significant was the formation of heterojunction structure between Ag3PO4 and g-C3N4, which efficiently promoted the separation of electron-hole pairs by a Z-scheme mechanism and ultimately enhanced the photocatalytic CO2 reduction performance of the Ag3PO4/g-C3N4. The optimal Ag3PO4/g-C3N4 photocatalyst showed a CO2 conversion rate of 57.5 μmol · h(-1) · gcat(-1), which was 6.1 and 10.4 times higher than those of g-C3N4 and P25, respectively, under simulated sunlight irradiation. The work found a new application of the photocatalyst, Ag3PO4/g-C3N4, in simultaneous environmental protection and energy production.

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Metadata

Authors
He, Y., Zhang, L., Teng, B., & Fan, M.
Venue
Environmental Science & Technology
Published
2014-12-17
Volume
49
Issue
1
Pages
649-656
ISSN
  • 0013-936X (ISSN-L)
  • 1520-5851
OpenAlex
W2313235764
Cited by
892
References
2
FWCI
22.92
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: New Application of Z-Scheme Ag3PO4/g-C3N4Composite in Converting CO2to Fuel. https://app.cochat.ai/papers/10.1021/es5046309
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He, Y., Zhang, L., Teng, B., & Fan, M. (2015). New Application of Z-Scheme Ag3PO4/g-C3N4Composite in Converting CO2to Fuel. Environmental Science & Technology. https://doi.org/10.1021/es5046309

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