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Reaction of Naphthalene and Its Derivatives with Hydroxyl Radicals in the Gas Phase

Bunce, Nigel J., Liu, Lina, Zhu, Jiang, Lane, Douglas A.·1997·Environmental Science & Technology

Abstract

Naphthalene is the most abundant polycyclic aromatic hydrocarbon (PAH) found in urban air. It is reactive in the atmosphere under ambient conditions, its chief reaction partner being the hydroxyl radical, OH • . In this work, the reactions of OH • with naphthalene, 1- and 2-naphthol, and 1- and 2-nitronaphthalene were studied in a 9.4 m 3 smog chamber. Relative rates of reaction accorded well with previous studies and allowed estimates to be made of the atmospheric lifetimes of these compounds. Numerous oxidation products were identified, and mechanisms proposed for their formation were based on the further transformation of benzocyclohexadienyl radicals formed by addition of OH • to naphthalene. The naphthols and nitronaphthalenes were deduced not to be on the major reaction pathway to the more oxidized products. Because of the high reactivity of PAH in air, we suggest that priority be given to identifying and quantitating their reaction products, some of which may be relatively persistent air toxics.

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Metadata

Authors
Bunce, N. J., Liu, L., Zhu, J., & Lane, D. A.
Venue
Environmental Science & Technology
Published
1997-07-30
Volume
31
Issue
8
Pages
2252-2259
ISSN
  • 0013-936X (ISSN-L)
  • 1520-5851
OpenAlex
W1966678616
Cited by
168
References
0
FWCI
3.19
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Reaction of Naphthalene and Its Derivatives with Hydroxyl Radicals in the Gas Phase. https://app.cochat.ai/papers/10.1021/es960813g
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Bunce, N. J., Liu, L., Zhu, J., & Lane, D. A. (1997). Reaction of Naphthalene and Its Derivatives with Hydroxyl Radicals in the Gas Phase. Environmental Science & Technology. https://doi.org/10.1021/es960813g

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