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Infrared study of ambient-temperature chloroaluminates as a function of melt acidity
Abstract
The infrared spectra of butyl pyridinium chloride/aluminum chloride and 1-methyl 3-ethyl imadazolium chloride/aluminum chloride room temperature molten salts have been examined over a range of mole ratios (acidities). Bands observed in the 4000-630/cm range have been assigned and spectral changes attributed to the formation of ion pairs, which may involve distortion of the aromatic ring since there is an accompanying loss of aromatic character. This effect is more pronounced in the imidazolium melts where more highly basic melts can be studied due to the greater liquidus range. Several isobestic points are reported.
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Citations
Cited by
Room-Temperature Ionic Liquids: Solvents for Synthesis and Catalysis. 2
Hallett, J. P., & Welton, T. (2011) · Chemical Reviews · doi:10.1021/cr1003248 · Cited by 12,578
Air and water stable 1-ethyl-3-methylimidazolium based ionic liquids
Wilkes, J. S., & Zaworotko, M. J. (1992) · Journal of the Chemical Society, Chemical Communications · doi:10.1039/c39920000965 · Cited by 1,883
Ionic liquids: perspectives for organic and catalytic reactions
Olivier-Bourbigou, H., & Magna, L. (2002) · Journal of Molecular Catalysis A: Chemical · doi:10.1016/s1381-1169(01)00465-4 · Cited by 927
Vibrational Spectroscopy of Ionic Liquids
Paschoal, V. H., Faria, L. F. O., & Ribeiro, M. C. C. (2017) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00461 · Cited by 414
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Candeias, N. R., Branco, L. C., Gois, P. M. P., Afonso, C. A. M., & Trindade, A. F. (2009) · Chemical Reviews · doi:10.1021/cr800462w · Cited by 403
Metadata
- Authors
- Tait, S., & Osteryoung, R. A.
- Venue
- Inorganic Chemistry
- Publisher
- American Chemical Society (ACS)
- Published
- 1984-12
- Volume
- 23
- Issue
- 25
- Pages
- 4352-4360
- ISSN
- 0020-1669 (ISSN-L)
- 1520-510X
- OpenAlex
- W3182364981
- Cited by
- 173
- References
- 0
- FWCI
- 2.31
- Type
- journal article
- Language
- en
- Open access
- closed
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- Tait, S., & Osteryoung, R. A. (1984). Infrared study of ambient-temperature chloroaluminates as a function of melt acidity. Inorganic Chemistry. https://doi.org/10.1021/ic00193a049
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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