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In2(OH)3(BDC)1.5 (BDC = 1,4-Benzendicarboxylate): An In(III) Supramolecular 3D Framework with Catalytic Activity
Abstract
The new hybrid inorganic-organic polymer In(2)(OH)(3)[O(4)C(8)H(4)](1.5) has been hydrothermally obtained. Conditions for the synthesis are reported. The crystal structure of this material has been established by single-crystal X-ray diffraction: it is monoclinic, with space group P2(1)/c (Nomicron. 14), a = 6.772(1) A, b = 10.329(2) A, c = 20.152(3) A, beta = 97.573(3) degrees. The In atoms are octahedrally coordinated by three hydroxide groups and three different molecules of carboxylate ligand. The resulting polymeric 3D structure can be envisaged as having been generated from a honeycomb (6,3) 2D that is cross-linked by the BDC organic anions. Data of IR and TGA-DTA studies, as well as the results of reduction of nitroaromatics and selective oxidation of organic sulfide reactions catalyzed by the new material, are reported.
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Furukawa, H., Cordova, K. E., O’Keeffe, M., & Yaghi, O. M. (2013) · Science · doi:10.1126/science.1230444 · Cited by 16,945
Functional Porous Coordination Polymers
Kitagawa, S., Kitaura, R., & Noro, S. (2004) · Angewandte Chemie International Edition · doi:10.1002/anie.200300610 · Cited by 11,071
Metal-organic framework materials as catalysts
Lee, J., Farha, O. K., Roberts, J., Scheidt, K. A., Nguyen, S. T., & Hupp, J. T. (2009) · Chemical Society Reviews · doi:10.1039/b807080f · Cited by 7,969
Engineering coordination polymers towards applications
Janiak, C. (2003) · Dalton Transactions · doi:10.1039/b305705b · Cited by 3,374
Industrial applications of metal–organic frameworks
Czaja, A. U., Trukhan, N., & Müller, U. (2009) · Chemical Society Reviews · doi:10.1039/b804680h · Cited by 2,341
Metal–organic and covalent organic frameworks as single-site catalysts
Rogge, S. M. J., Bavykina, A., Hajek, J., Garcia, H., Olivos-Suarez, A. I., Sepúlveda-Escribano, A., Vimont, A., Clet, G., Bazin, P., Kapteijn, F., et al. (2017) · Chemical Society Reviews · doi:10.1039/c7cs00033b · Cited by 1,077
Bauer, S., Serre, C., Devic, T., Horcajada, P., Marrot, J., Férey, G., & Stock, N. (2008) · Inorganic Chemistry · doi:10.1021/ic800538r · Cited by 620
Serre, C., Millange, F., Surblé, S., & Férey, G. (2004) · Angewandte Chemie International Edition · doi:10.1002/anie.200454250 · Cited by 592
Metadata
- Authors
- Gomez-Lor, B., Gutiérrez-Puebla, E., Iglesias, M., Monge, M. A., Ruiz-Valero, C., & Snejko, N.
- Venue
- Inorganic Chemistry
- Publisher
- American Chemical Society (ACS)
- Published
- 2002-04-09
- Volume
- 41
- Issue
- 9
- Pages
- 2429-2432
- ISSN
- 0020-1669 (ISSN-L)
- 1520-510X
- OpenAlex
- W1974964963
- Cited by
- 227
- References
- 0
- FWCI
- 10.68
- Type
- journal article
- Language
- en
- Open access
- closed
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