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Toward a Molecular Photochemical Device: A Triad for Photoinduced Charge Separation Based on a Platinum Diimine Bis(acetylide) Chromophore

McGarrah, James E., Kim, Yong-Joo, Hissler, Muriel, Eisenberg, Richard·2001·Inorganic Chemistry

Abstract

A donor−chromophore−acceptor triad (D−C−A) in which the chromophore is a Pt diimine bis(acetylide) moiety (red), the donor is phenothiazine (blue), and the acceptor is nitrophenyl (green) has been synthesized and studied spectroscopically. Irradiation leads to a charge-separated state that has a 70 ns lifetime as measured by transient absorption spectroscopy.

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Metadata

Authors
McGarrah, J. E., Kim, Y.-J., Hissler, M., & Eisenberg, R.
Venue
Inorganic Chemistry
Published
2001-07-27
Volume
40
Issue
18
Pages
4510-4511
ISSN
  • 0020-1669 (ISSN-L)
  • 1520-510X
OpenAlex
W2088665773
Cited by
398
References
0
FWCI
7.11
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Toward a Molecular Photochemical Device: A Triad for Photoinduced Charge Separation Based on a Platinum Diimine Bis(acetylide) Chromophore. https://app.cochat.ai/papers/10.1021/ic015559u
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McGarrah, J. E., Kim, Y.-J., Hissler, M., & Eisenberg, R. (2001). Toward a Molecular Photochemical Device: A Triad for Photoinduced Charge Separation Based on a Platinum Diimine Bis(acetylide) Chromophore. Inorganic Chemistry. https://doi.org/10.1021/ic015559u

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Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.