The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Comparative Study of the Coordination Chemistry and Lactide Polymerization of Alkoxide and Amide Complexes of Zinc and Magnesium with a β-Diiminato Ligand Bearing Ether Substituents
Abstract
A series of beta-diiminato complexes of the form (BDI-3)MX where (BDI-3) = [CH(CMeNC(6)H(4)-2-OMe)(2)]; M = Zn, Mg; X = O(i)()Pr, O(t)()Bu, or N(SiMe(3))(2) has been synthesized. The (BDI-3) ligand is bidentate in (BDI-3)ZnN(SiMe(3))(2) and tetradentate in (BDI-3)MgN(SiMe(3))(2). The alkoxide complexes are shown to be active for lactide polymerization. Polymerization of rac-lactide with (BDI-3)ZnO(i)Pr gives a moderate preference for heterotactic PLA. Polymerization of rac-lactide with [(BDI-3)MgO(t)Bu](2) shows a slight preference for heterotactic PLA in CH(2)Cl(2) but is highly stereoselective in THF in the production of heterotactic PLA.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Polymerization of Lactide with Zinc and Magnesium β-Diiminate Complexes: Stereocontrol and Mechanism
Chamberlain, B. M., Cheng, M., Moore, D. R., Ovitt, T. M., Lobkovsky, E. B., & Coates, G. W. (2001) · Journal of the American Chemical Society · doi:10.1021/ja003851f · Cited by 1,207
Cited by
Complexes of Mg, Ca and Zn as homogeneous catalysts for lactide polymerization
Wheaton, C. A., Hayes, P. G., & Ireland, B. J. (2009) · Dalton Transactions · doi:10.1039/b819107g · Cited by 438
Crimmin, M. R., Arrowsmith, M., Barrett, A. G. M., Casely, I. J., Hill, M. S., & Procopiou, P. A. (2009) · Journal of the American Chemical Society · doi:10.1021/ja9003377 · Cited by 278
Darensbourg, D. J., Choi, W., Karroonnirun, O., & Bhuvanesh, N. (2008) · Macromolecules · doi:10.1021/ma800078t · Cited by 260
Dyer, H. E., Huijser, S., Susperregui, N., Bonnet, F., Schwarz, A. D., Duchateau, R., Maron, L., & Mountford, P. (2010) · Organometallics · doi:10.1021/om100513j · Cited by 158
Thevenon, A., Romain, C., Bennington, M. S., White, A. J. P., Davidson, H. J., Brooker, S., & Williams, C. K. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201602930 · Cited by 151
Metadata
- Authors
- Chisholm, M. H., Gallucci, J. C., & Phomphrai, K.
- Venue
- Inorganic Chemistry
- Publisher
- American Chemical Society (ACS)
- Published
- 2005-09-24
- Volume
- 44
- Issue
- 22
- Pages
- 8004-8010
- ISSN
- 0020-1669 (ISSN-L)
- 1520-510X
- OpenAlex
- W2043630753
- Cited by
- 229
- References
- 1
- FWCI
- 5.71
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
