The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Size and Surface Effects of Prussian Blue Nanoparticles Protected by Organic Polymers
Abstract
Prussian blue (PB) nanoparticles protected by organic polymers such as poly(vinylpyrrolidone) (PVP) and poly(diallyldimethylammonium chloride) (PDDA) were prepared. Different experimental conditions (concentrations of Fe ions and feed ratios of Fe to the polymers) have been investigated to control the size of the PB nanoparticles. For example, the averaged dimensions of the PB nanoparticles were tuned from 12 to 27 nm by use of PVP in the different conditions. Addition of PDDA produced the PB nanoparticles with very small dimensions (5-8 nm) by an effective electrostatic interaction. We found that the surface environments of the PB nanoparticles affect the inherent properties of PB. The shifts of charge transfer (CT) absorptions from Fe(2+) to Fe(3+) in the PB nanoparticles resulted from the surface-protecting polymers. Especially, the PB nanoparticles with the PVP protection show high solubility in a variety of organic solvents and a solvent-dependent CT absorption. Measurement of the magnetic properties of the PB nanoparticles showed unprecedented size-dependency, surface effect, and superparamagnetic properties.
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Cites
Monodisperse FePt Nanoparticles and Ferromagnetic FePt Nanocrystal Superlattices
Sun, S., Murray, C. B., Weller, D., Folks, L., & Moser, A. (2000) · Science · doi:10.1126/science.287.5460.1989 · Cited by 6,137
Cited by
Synthesis of Prussian Blue Nanoparticles with a Hollow Interior by Controlled Chemical Etching
Hu, M., Furukawa, S., Ohtani, R., Sukegawa, H., Nemoto, Y., Reboul, J., Kitagawa, S., & Yamauchi, Y. (2012) · Angewandte Chemie International Edition · doi:10.1002/anie.201105190 · Cited by 532
Self-citationNanoscale metal–organic frameworks for phototherapy of cancer
Lan, G., Ni, K., & Lin, W. (2019) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2017.09.007 · Cited by 420
Novel Route to Size-Controlled Fe–MIL-88B–NH2 Metal–Organic Framework Nanocrystals
Pham, M.-H., Vuong, G.-T., Vu, A.-T., & Do, T.-O. (2011) · Langmuir · doi:10.1021/la203570h · Cited by 273
Nanoarchitectonics: A New Materials Horizon for Prussian Blue and Its Analogues
Azhar, A., Li, Y., Cai, Z., Zakaria, M. B., Masud, M. K., Hossain, M. S. A., Kim, J., Zhang, W., Na, J., Yamauchi, Y., et al. (2019) · Bulletin of the Chemical Society of Japan · doi:10.1246/bcsj.20180368 · Cited by 267
Metadata
- Authors
- Uemura, T., Ohba, M., & Kitagawa, S.
- Venue
- Inorganic Chemistry
- Publisher
- American Chemical Society (ACS)
- Published
- 2004-10-13
- Volume
- 43
- Issue
- 23
- Pages
- 7339-7345
- ISSN
- 0020-1669 (ISSN-L)
- 1520-510X
- OpenAlex
- W2079871184
- Cited by
- 210
- References
- 1
- FWCI
- 7.36
- Type
- journal article
- Language
- en
- Open access
- closed
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