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Facile Controlled Synthesis of MnO2 Nanostructures of Novel Shapes and Their Application in Batteries

Cheng, Fangyi, Zhao, Jianzhi, Song, Wene, Li, Chunsheng, Ma, Hua, Chen, Jun, Shen, Panwen·2006·Inorganic Chemistry

Abstract

In this paper, MnO2 nanomaterials of different crystallographic types and crystal morphologies have been selectively synthesized via a facile hydrothermal route and electrochemically investigated as the cathode active materials of primary and rechargeable batteries. Beta-MnO2 nano/microstructures, including one-dimensional (1-D) nanowires, nanorods, and nanoneedles, as well as 2-D hexagramlike and dendritelike hierarchical forms, were obtained by simple hydrothermal decomposition of an Mn(NO3)2 solution under controlled reaction conditions. Alpha- and gamma-MnO2 nanowires and nanorods were also prepared on the basis of previous literature. The as-synthesized samples were characterized by instrumental analyses such as XRD, SEM, TEM, and HRTEM. Furthermore, the obtained 1-D alpha- and gamma-MnO2 nanostructures were found to exhibit favorable discharge performance in both primary alkaline Zn-MnO2 cells and rechargeable Li-MnO2 cells, showing their potential applications in high-energy batteries.

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Metadata

Authors
Cheng, F., Zhao, J., Song, W., Li, C., Ma, H., Chen, J., & Shen, P.
Venue
Inorganic Chemistry
Published
2006-02-02
Volume
45
Issue
5
Pages
2038-2044
ISSN
  • 0020-1669 (ISSN-L)
  • 1520-510X
OpenAlex
W1970049711
Cited by
500
References
2
FWCI
26.65
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Facile Controlled Synthesis of MnO2 Nanostructures of Novel Shapes and Their Application in Batteries. https://app.cochat.ai/papers/10.1021/ic051715b
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Cheng, F., Zhao, J., Song, W., Li, C., Ma, H., Chen, J., & Shen, P. (2006). Facile Controlled Synthesis of MnO2 Nanostructures of Novel Shapes and Their Application in Batteries. Inorganic Chemistry. https://doi.org/10.1021/ic051715b

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