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Hydrogen Adsorption in an Interpenetrated Dynamic Metal−Organic Framework
Abstract
A metal-organic framework Zn(NDC)(4,4'-Bpe)(0.5).xG [NDC = 2,6-naphthalenedicarboxylate; 4,4'-Bpe = 4,4'-trans-bis(4-pyridyl)ethylene; G = guest molecules] has been synthesized, structurally characterized, and rationalized to be a two-interpenetrated elongated primitive cubic net. Powder X-ray diffraction and adsorption studies reveal the dynamic feature of the framework, which can take up hydrogen of about 2.0 wt % at 77 K and 40 bar and 0.3 wt % at 298 K and 65 bar.
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Citations
Cited by
Han, S. S., Mendoza-Cortés, J. L., & Goddard III, W. A. (2009) · Chemical Society Reviews · doi:10.1039/b802430h · Cited by 594
Nanoporous Polymers for Hydrogen Storage
Germain, J., Fréchet, J. M. J., & Svec, F. (2009) · Small · doi:10.1002/smll.200801762 · Cited by 432
Ni1-xPtx (x = 0−0.12) Hollow Spheres as Catalysts for Hydrogen Generation from Ammonia Borane
Cheng, F., Ma, H., Li, Y., & Chen, J. (2007) · Inorganic Chemistry · doi:10.1021/ic061712e · Cited by 349
Metadata
- Authors
- Chen, B., Ma, S., Zapata, F., Lobkovsky, E. B., & Yang, J.
- Venue
- Inorganic Chemistry
- Publisher
- American Chemical Society (ACS)
- Published
- 2006-06-23
- Volume
- 45
- Issue
- 15
- Pages
- 5718-5720
- ISSN
- 0020-1669 (ISSN-L)
- 1520-510X
- OpenAlex
- W2020772475
- Cited by
- 194
- References
- 0
- FWCI
- 17.96
- Type
- journal article
- Language
- en
- Open access
- closed
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- Chen, B., Ma, S., Zapata, F., Lobkovsky, E. B., & Yang, J. (2006). Hydrogen Adsorption in an Interpenetrated Dynamic Metal−Organic Framework. Inorganic Chemistry. https://doi.org/10.1021/ic060437t
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