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Formation of Hollow Ni2P Nanoparticles Based on the Nanoscale Kirkendall Effect

Chiang, Ray-Kuang, Chiang, Ray-Tung·2007·Inorganic Chemistry

Abstract

Colloidal hollow nanoparticles (NPs) of Ni2P have been prepared by a one-pot reaction from a mixture of nickel acetate, oleylamine, trioctylphosphine (TOP), and 1-octadecene. The mechanism to the hollow structure is related to the nanoscale Kirkendall effect. The process contains two important steps. First, oleylamine-stabilized Ni NPs were formed, which can protect them from TOP etching and slow down the inward diffusion of P atoms. Second, the solid-state reaction between the Ni NPs occurred when the TOP concentration and the reaction temperature were correctly adjusted.

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Authors
Chiang, R.-K., & Chiang, R.-T.
Venue
Inorganic Chemistry
Published
2006-12-19
Volume
46
Issue
2
Pages
369-371
ISSN
  • 0020-1669 (ISSN-L)
  • 1520-510X
OpenAlex
W2033688638
Cited by
266
References
0
FWCI
8.68
Type
journal article
Language
en
Open access
closed

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