The DOI matches its Crossref record; 5 of the 5 references it cites were found in a registry or an index.
Bimetallic Ni−Pt Nanocatalysts for Selective Decomposition of Hydrazine in Aqueous Solution to Hydrogen at Room Temperature for Chemical Hydrogen Storage
Abstract
The design and development of alloy catalysts has been a focus of intense interest because suitable selection and control over the composition of alloy catalysts can result in greatly improved activity and selectivity, while it is unusual that the combination of two inactive metals gives a highly active catalyst. In this work, we found that Ni-Pt bimetallic nanocatalysts, with a platinum content as low as 7 mol %, prepared by the coreduction of the corresponding metal chlorides, exhibit excellent catalytic activity to the decomposition of hydrous hydrazine, producing hydrogen with a 100% selectivity at room temperature, whereas the corresponding single-component nickel and platinum counterparts are inactive for this reaction. These results provide new possibilities for searching heterometallic catalysts. The present catalyst with low noble-metal content promotes the practical use of the hydrogen-storage system based on the catalytic complete decomposition of hydrazine in aqueous solution at ambient conditions.
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Cites
Improved Oxygen Reduction Activity on Pt 3 Ni(111) via Increased Surface Site Availability
Stamenkovic, V. R., Fowler, B., Mun, B. S., Wang, G., Ross, P. N., Lucas, C. A., & Marković, N. M. (2007) · Science · doi:10.1126/science.1135941 · Cited by 4,421
Nanoalloys: From Theory to Applications of Alloy Clusters and Nanoparticles
Ferrando, R., Jellinek, J., & Johnston, R. L. (2008) · Chemical Reviews · doi:10.1021/cr040090g · Cited by 3,690
Trends in electrocatalysis on extended and nanoscale Pt-bimetallic alloy surfaces
Stamenkovic, V. R., Mun, B. S., Arenz, M., Mayrhofer, K. J. J., Lucas, C. A., Wang, G., Ross, P. N., & Markovic, N. M. (2007) · Nature Materials · doi:10.1038/nmat1840 · Cited by 3,252
Alloys of platinum and early transition metals as oxygen reduction electrocatalysts
Greeley, J., Stephens, I. E. L., Bondarenko, A. S., Johansson, T. P., Hansen, H. A., Jaramillo, T. F., Rossmeisl, J., Chorkendorff, I., & Nørskov, J. K. (2009) · Nature Chemistry · doi:10.1038/nchem.367 · Cited by 3,203
B–N compounds for chemical hydrogenstorage
Hamilton, C. W., Baker, R. T., Staubitz, A., & Manners, I. (2009) · Chem. Soc. Rev. · doi:10.1039/b800312m · Cited by 1,087
Cited by
Review of Pt-Based Bimetallic Catalysis: From Model Surfaces to Supported Catalysts
Yu, W., Porosoff, M. D., & Chen, J. G. (2012) · Chemical Reviews · doi:10.1021/cr300096b · Cited by 1,253
Ammonia and related chemicals as potential indirect hydrogen storage materials
Lan, R., Irvine, J. T. S., & Tao, S. (2012) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2011.10.004 · Cited by 1,207
Ni-based bimetallic heterogeneous catalysts for energy and environmental applications
De, S., Zhang, J., Luque, R., & Yan, N. (2016) · Energy & Environmental Science · doi:10.1039/c6ee02002j · Cited by 786
Synergistic Catalysis over Bimetallic Alloy Nanoparticles
Singh, A. K., & Xu, Q. (2013) · ChemCatChem · doi:10.1002/cctc.201200591 · Cited by 698
Self-citationHydrogen storage: beyond conventional methods
Dalebrook, A. F., Gan, W., Grasemann, M., Moret, S., & Laurenczy, G. (2013) · Chemical Communications · doi:10.1039/c3cc43836h · Cited by 503
Metadata
- Authors
- Singh, S. K., & Xu, Q.
- Venue
- Inorganic Chemistry
- Publisher
- American Chemical Society (ACS)
- Published
- 2010-06-02
- Volume
- 49
- Issue
- 13
- Pages
- 6148-6152
- ISSN
- 0020-1669 (ISSN-L)
- 1520-510X
- OpenAlex
- W2073096525
- Cited by
- 168
- References
- 5
- FWCI
- 6.64
- Type
- journal article
- Language
- en
- Open access
- closed
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- Singh, S. K., & Xu, Q. (2010). Bimetallic Ni−Pt Nanocatalysts for Selective Decomposition of Hydrazine in Aqueous Solution to Hydrogen at Room Temperature for Chemical Hydrogen Storage. Inorganic Chemistry. https://doi.org/10.1021/ic1007654
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
