The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
Carbene Stabilization of Highly Reactive Main-Group Molecules
Abstract
This article highlights recent efforts of this laboratory in the stabilization of highly reactive, low-oxidation-state, main-group molecules using bulky N-heterocyclic carbene ligands [L: = :C{N(2,6-Pr(i)(2)C(6)H(3))CH}(2); L': = :C{N(2,4,6-Me(3)C(6)H(2))CH}(2); L'': = :C{(i-Pr)NC(Me)}(2)]. The syntheses, structures, and computational studies of carbene-stabilized neutral diborenes [L:(H)B═B(H):L and L':(H)B═B(H):L'], a neutral Ga(6) octahedron (L'':Ga[Ga(4)Mes(4)]Ga:L''), disilicon (L:Si═Si:L), bis-silylene [L:(Cl)Si-Si(Cl):L], dipnictogens (L:E-E:L, E = P, As; L':P-P:L'), and parent phosphinidene (L:PH) are discussed. Some of the unique challenges associated with this "carbene-stabilization" strategy are also presented.
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(1999) · Choice Reviews Online · doi:10.5860/choice.37-0940 · Cited by 14,314
Nucleus-Independent Chemical Shifts (NICS) as an Aromaticity Criterion
Chen, Z., Wannere, C. S., Corminboeuf, C., Puchta, R., & Schleyer, P. V. R. (2005) · Chemical Reviews · doi:10.1021/cr030088+ · Cited by 3,847
Cited by
Cyclic (Alkyl)(amino)carbenes (CAACs): Recent Developments
Melaimi, M., Jazzar, R., Soleilhavoup, M., & Bertrand, G. (2017) · Angewandte Chemie International Edition · doi:10.1002/anie.201702148 · Cited by 788
N-Heterocyclic Carbene—Main-Group Chemistry: A Rapidly Evolving Field
Wang, Y., & Robinson, G. H. (2014) · Inorganic Chemistry · doi:10.1021/ic502231m · Cited by 266
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Metadata
- Authors
- Wang, Y., & Robinson, G. H.
- Venue
- Inorganic Chemistry
- Publisher
- American Chemical Society (ACS)
- Published
- 2011-06-02
- Volume
- 50
- Issue
- 24
- Pages
- 12326-12337
- ISSN
- 0020-1669 (ISSN-L)
- 1520-510X
- OpenAlex
- W2319605794
- Cited by
- 380
- References
- 2
- FWCI
- 28.36
- Type
- journal article
- Language
- en
- Open access
- closed
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- Wang, Y., & Robinson, G. H. (2011). Carbene Stabilization of Highly Reactive Main-Group Molecules. Inorganic Chemistry. https://doi.org/10.1021/ic200675u
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