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Synthesis, Structure, and Metalation of Two New Highly Porous Zirconium Metal–Organic Frameworks
Abstract
Three new metal-organic frameworks [MOF-525, Zr(6)O(4)(OH)(4)(TCPP-H(2))(3); MOF-535, Zr(6)O(4)(OH)(4)(XF)(3); MOF-545, Zr(6)O(8)(H(2)O)(8)(TCPP-H(2))(2), where porphyrin H(4)-TCPP-H(2) = (C(48)H(24)O(8)N(4)) and cruciform H(4)-XF = (C(42)O(8)H(22))] based on two new topologies, ftw and csq, have been synthesized and structurally characterized. MOF-525 and -535 are composed of Zr(6)O(4)(OH)(4) cuboctahedral units linked by either porphyrin (MOF-525) or cruciform (MOF-535). Another zirconium-containing unit, Zr(6)O(8)(H(2)O)(8), is linked by porphyrin to give the MOF-545 structure. The structure of MOF-525 was obtained by analysis of powder X-ray diffraction data. The structures of MOF-535 and -545 were resolved from synchrotron single-crystal data. MOF-525, -535, and -545 have Brunauer-Emmett-Teller surface areas of 2620, 1120, and 2260 m(2)/g, respectively. In addition to their large surface areas, both porphyrin-containing MOFs are exceptionally chemically stable, maintaining their structures under aqueous and organic conditions. MOF-525 and -545 were metalated with iron(III) and copper(II) to yield the metalated analogues without losing their high surface area and chemical stability.
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Cited by
Xu, H.-Q., Hu, J., Wang, D., Li, Z., Zhang, Q., Luo, Y., Yu, S.-H., & Jiang, H.-L. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b08773 · Cited by 1,166
Park, J., Jiang, Q., Feng, D., Mao, L., & Zhou, H.-C. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.6b00007 · Cited by 915
Stable Metal–Organic Frameworks with Group 4 Metals: Current Status and Trends
Yuan, S., Qin, J.-S., Lollar, C. T., & Zhou, H.-C. (2018) · ACS Central Science · doi:10.1021/acscentsci.8b00073 · Cited by 561
Wang, Y.-R., Huang, Q., He, C.-T., Chen, Y., Liu, J., Shen, F.-C., & Lan, Y.-Q. (2018) · Nature Communications · doi:10.1038/s41467-018-06938-z · Cited by 482
Wang, B., Yang, Q., Guo, C., Sun, Y., Xie, L.-H., & Li, J.-R. (2017) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.7b00918 · Cited by 423
Metadata
- Authors
- Morris, W., Volosskiy, B., Demir, S., Gándara, F., McGrier, P. L., Furukawa, H., Cascio, D., Stoddart, J. F., & Yaghi, O. M.
- Venue
- Inorganic Chemistry
- Publisher
- American Chemical Society (ACS)
- Published
- 2012-06-07
- Volume
- 51
- Issue
- 12
- Pages
- 6443-6445
- ISSN
- 0020-1669 (ISSN-L)
- 1520-510X
- OpenAlex
- W1967812076
- Cited by
- 906
- References
- 0
- FWCI
- 30.94
- Type
- journal article
- Language
- en
- Open access
- closed
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- Morris, W., Volosskiy, B., Demir, S., Gándara, F., McGrier, P. L., Furukawa, H., Cascio, D., Stoddart, J. F., & Yaghi, O. M. (2012). Synthesis, Structure, and Metalation of Two New Highly Porous Zirconium Metal–Organic Frameworks. Inorganic Chemistry. https://doi.org/10.1021/ic300825s
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