The DOI matches its Crossref record; 27 of the 27 references it cites were found in a registry or an index.
Fabrication of Novel p-BiOI/n-ZnTiO3 Heterojunction for Degradation of Rhodamine 6G under Visible Light Irradiation
Abstract
With the purpose of efficient electron-hole separation and enhancement of photocatalytic performance in the visible region, we have fabricated a novel p-BiOI/n-ZnTiO3 heterojunction by a precipitation-deposition method and studied its activity toward dye degradation. The physicochemical characteristics of the fabricated BiOI/ZnTiO3 heterojunctions were surveyed by powder X-ray diffraction pattern (PXRD), BET-surface area, diffuse reflectance UV-vis (DRUV-vis), field emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM), photoluminescence spectroscopy (PL spectra), X-ray photoelectron spectroscopy (XPS), and photoelectrochemical measurement. The photosensitization effect of BiOI enhanced the spectral response of ZnTiO3 from UV to visible region, making all the BiOI/ZnTiO3 heterojunctions active under visible light. The PEC measurement confirmed the p-type character of BiOI and n-type character of ZnTiO3. The optimal amount of BiOI in BiOI/ZnTiO3 heterojunctions was found to be 50% which degraded 82% of 50 ppm Rh 6G under visible light irradiation. The degradation rate of 50% BiOI/ZnTiO3 heterojunction was found to be 9.8 and 11.1 times higher than that of bare BiOI and ZnTiO3, respectively. The photosensitization effect of BiOI and the formed heterojunction between p-type BiOI and n-type ZnTiO3 contribute to improved electron-hole separation and enhancement in photocatalytic activity.
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Metadata
- Authors
- Reddy, K. H., Martha, S., & Parida, K. M.
- Venue
- Inorganic Chemistry
- Publisher
- American Chemical Society (ACS)
- Published
- 2013-05-14
- Volume
- 52
- Issue
- 11
- Pages
- 6390-6401
- ISSN
- 0020-1669 (ISSN-L)
- 1520-510X
- OpenAlex
- W2316893673
- Cited by
- 257
- References
- 27
- FWCI
- 11.66
- Type
- journal article
- Language
- en
- Open access
- closed
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