The DOI matches its Crossref record; 45 of the 45 references it cites were found in a registry or an index.
Highly Selective Luminescent Sensing of Fluoride and Organic Small-Molecule Pollutants Based on Novel Lanthanide Metal–Organic Frameworks
Abstract
Two novel isostructural lanthanide metal-organic frameworks (Ln-MOFs), [Ln2(BPDC)(BDC)2(H2O)2]n (Ln = Eu (1) and Tb (2)), have been successfully synthesized via a mixed ligand approach using 2,2'-bipyridine-3,3'-dicarboxylic acid (H2BPDC) and 1,4-benzenedicarboxylic acid (H2BDC) under hydrothermal conditions. Structural analysis shows that two lanthanide ions are 4-fold linked by two κ(1)-κ(1)-μ2 carboxylates from BDC(2-) and the other two κ(2)-κ(1)-μ2 carboxylates from BPDC(2-) to form a binuclear core. The binuclear units are further connected by BDC(2-) and BPDC(2-) to build a three-dimensional framework possessing tfz-d topology with the short (Schläfli) vertex symbol {4(3)}2{4(6)·6(18)·8(4)}. Moreover, isostructural doped Ln-MOFs [Eu(2x)Tb2(1-x)(BPDC)(BDC)2(H2O)2]n (x = 0.1 (1a), 0.3 (1b), 0.5 (1c), 0.7 (1d), and 0.9 (1e)) were also successfully synthesized. Thermal gravimetric analyses (TGA) reveal high thermal stability of these Ln-MOFs. Luminescent measurements indicate that the characteristic sharp emission bands of Eu(3+) and Tb(3+) ions are simultaneously observed in 1a-e. Further luminescent studies reveal that 1, 2, and 1a not only display a high-sensitivity sensing function with respect to fluoride but also exhibit significant solvent-dependent luminescent response to small-molecule pollutants, such as formaldehyde, acetonitrile, and acetone.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Sheldrick, G. M. (2008) · Acta Crystallographica Section A Foundations of Crystallography · doi:10.1107/s0108767307043930 · Cited by 87,804
OLEX2 : a complete structure solution, refinement and analysis program
Dolomanov, O. V., Bourhis, L. J., Gildea, R. J., Howard, J. A. K., & Puschmann, H. (2009) · Journal of Applied Crystallography · doi:10.1107/s0021889808042726 · Cited by 32,811
Metal–Organic Framework Materials as Chemical Sensors
Kreno, L. E., Leong, K., Farha, O. K., Allendorf, M., Van Duyne, R. P., & Hupp, J. T. (2012) · Chemical Reviews · doi:10.1021/cr200324t · Cited by 7,136
Luminescent Functional Metal–Organic Frameworks
Cui, Y., Yue, Y., Qian, G., & Chen, B. (2012) · Chemical Reviews · doi:10.1021/cr200101d · Cited by 5,697
Luminescent metal–organic frameworks
Allendorf, M. D., Bauer, C. A., Bhakta, R. K., & Houk, R. J. T. (2009) · Chemical Society Reviews · doi:10.1039/b802352m · Cited by 4,960
Potential applications of metal-organic frameworks
Kuppler, R. J., Timmons, D. J., Fang, Q.-R., Li, J.-R., Makal, T. A., Young, M. D., Yuan, D., Zhao, D., Zhuang, W., & Zhou, H.-C. (2009) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2009.05.019 · Cited by 1,659
Metal‐Organic Frameworks: A Rapidly Growing Class of Versatile Nanoporous Materials
Meek, S. T., Greathouse, J. A., & Allendorf, M. D. (2011) · Advanced Materials · doi:10.1002/adma.201002854 · Cited by 1,407
Lan, A., Li, K., Wu, H., Olson, D. H., Emge, T. J., Ki, W., Hong, M., & Li, J. (2009) · Angewandte Chemie International Edition · doi:10.1002/anie.200804853 · Cited by 1,237
A Luminescent Mixed-Lanthanide Metal–Organic Framework Thermometer
Cui, Y., Xu, H., Yue, Y., Guo, Z., Yu, J., Chen, Z., Gao, J., Yang, Y., Qian, G., & Chen, B. (2012) · Journal of the American Chemical Society · doi:10.1021/ja2108036 · Cited by 1,161
Old materials with new tricks: multifunctional open-framework materials
Maspoch, D., Ruiz-Molina, D., & Veciana, J. (2007) · Chemical Society Reviews · doi:10.1039/b501600m · Cited by 1,073
A Luminescent Microporous Metal−Organic Framework for the Recognition and Sensing of Anions
Chen, B., Wang, L., Zapata, F., Qian, G., & Lobkovsky, E. B. (2008) · Journal of the American Chemical Society · doi:10.1021/ja802035e · Cited by 1,014
Rational Synthesis of Noncentrosymmetric Metal–Organic Frameworks for Second-Order Nonlinear Optics
Wang, C., Zhang, T., & Lin, W. (2012) · Chemical Reviews · doi:10.1021/cr200252n · Cited by 1,005
Luminescent Open Metal Sites within a Metal–Organic Framework for Sensing Small Molecules
Chen, B., Yang, Y., Zapata, F., Lin, G., Qian, G., & Lobkovsky, E. B. (2007) · Advanced Materials · doi:10.1002/adma.200601838 · Cited by 954
Continuous Symmetry Measures. 5. The Classical Polyhedra
Pinsky, M. B., & Avnir, D. (1998) · Inorganic Chemistry · doi:10.1021/ic9804925 · Cited by 885
Zabrodsky, H., Peleg, S., & Avnir, D. (1992) · Journal of the American Chemical Society · doi:10.1021/ja00046a033 · Cited by 714
Muetterties, E. L., & Guggenberger, L. J. (1974) · Journal of the American Chemical Society · doi:10.1021/ja00813a017 · Cited by 694
Near-Infrared Luminescent Lanthanide MOF Barcodes
White, K. A., Chengelis, D. A., Gogick, K. A., Stehman, J., Rosi, N. L., & Petoud, S. (2009) · Journal of the American Chemical Society · doi:10.1021/ja907885m · Cited by 492
Sun, Y., Zhang, J., Chen, Y., & Yang, G. (2005) · Angewandte Chemie International Edition · doi:10.1002/anie.200500453 · Cited by 448
Cation Sensing by a Luminescent Metal–Organic Framework with Multiple Lewis Basic Sites
Tang, Q., Liu, S., Liu, Y., Miao, J., Li, S., Zhang, L., Shi, Z., & Zheng, Z. (2013) · Inorganic Chemistry · doi:10.1021/ic400029p · Cited by 404
Harbuzaru, B. V., Corma, A., Rey, F., Atienzar, P., Jordá, J. L., García, H., Ananias, D., Carlos, L. D., & Rocha, J. (2008) · Angewandte Chemie International Edition · doi:10.1002/anie.200704702 · Cited by 403
A Highly Porous Luminescent Terbium–Organic Framework for Reversible Anion Sensing
Wong, K. ‐., Law, G. ‐., Yang, Y. ‐., & Wong, W. ‐. (2006) · Advanced Materials · doi:10.1002/adma.200502138 · Cited by 387
A robust near infrared luminescent ytterbium metal–organic framework for sensing of small molecules
Guo, Z., Xu, H., Su, S., Cai, J., Dang, S., Xiang, S., Qian, G., Zhang, H., O’Keeffe, M., & Chen, B. (2011) · Chemical Communications · doi:10.1039/c1cc10897b · Cited by 361
Structures of high coordination complexes
Drew, M. G. B. (1977) · Coordination Chemistry Reviews · doi:10.1016/s0010-8545(00)80338-0 · Cited by 334
Lan, Y., Jiang, H., Li, S., & Xu, Q. (2011) · Advanced Materials · doi:10.1002/adma.201102880 · Cited by 333
Wang, J.-H., Li, M., & Li, D. (2013) · Chemical Science · doi:10.1039/c3sc00016h · Cited by 311
de Lill, D. T., de Bettencourt-Dias, A., & Cahill, C. L. (2007) · Inorganic Chemistry · doi:10.1021/ic062019u · Cited by 292
A Color‐Tunable Europium Complex Emitting Three Primary Colors and White Light
He, G., Guo, D., He, C., Zhang, X., Zhao, X., & Duan, C. (2009) · Angewandte Chemie International Edition · doi:10.1002/anie.200901266 · Cited by 250
Zhang, Z., Xiang, S., Rao, X., Zheng, Q., Fronczek, F. R., Qian, G., & Chen, B. (2010) · Chemical Communications · doi:10.1039/c0cc01236j · Cited by 242
Li, G., Hou, Z., Peng, C., Wang, W., Cheng, Z., Li, C., Lian, H., & Lin, J. (2010) · Advanced Functional Materials · doi:10.1002/adfm.201001114 · Cited by 230
Wu, P., Wang, J., He, C., Zhang, X., Wang, Y., Liu, T., & Duan, C. (2012) · Advanced Functional Materials · doi:10.1002/adfm.201102157 · Cited by 221
Torelli, S., Imbert, D., Cantuel, M., Bernardinelli, G., Delahaye, S., Hauser, A., Bünzli, J. G., & Piguet, C. (2005) · Chemistry - A European Journal · doi:10.1002/chem.200401158 · Cited by 188
Wu, P., Wang, J., Li, Y., He, C., Xie, Z., & Duan, C. (2011) · Advanced Functional Materials · doi:10.1002/adfm.201100115 · Cited by 185
Li, H., Shi, W., Zhao, K., Niu, Z., Li, H., & Cheng, P. (2013) · Chemistry – A European Journal · doi:10.1002/chem.201203487 · Cited by 168
Self-citationLiu, K., You, H., Zheng, Y., Jia, G., Song, Y., Huang, Y., Yang, M., Jia, J., Guo, N., & Zhang, H. (2010) · Journal of Materials Chemistry · doi:10.1039/b927465k · Cited by 149
Two novel MOF-74 analogs exhibiting unique luminescent selectivity
Liu, G.-L., Qin, Y.-J., Jing, L., Wei, G.-Y., & Li, H. (2012) · Chemical Communications · doi:10.1039/c2cc37140e · Cited by 137
Lanthanide(III)−Cobalt(II) Heterometallic Coordination Polymers with Radical Adsorption Properties
Zhao, X., Zhao, B., Ma, Y., Shi, W., Cheng, P., Jiang, Z., Liao, D., & Yan, S. (2007) · Inorganic Chemistry · doi:10.1021/ic7007446 · Cited by 121
Self-citationMicroporous lanthanide metal-organic frameworks
Chen, Y., & Ma, S. (2012) · Reviews in Inorganic Chemistry · doi:10.1515/revic-2012-0003 · Cited by 106
Bourdolle, A., Allali, M., Mulatier, J., Guennic, B. L., Zwier, J. M., Baldeck, P. L., Bünzli, J. G., Andraud, C., Lamarque, L., & Maury, O. (2011) · Inorganic Chemistry · doi:10.1021/ic200227b · Cited by 83
Hou, S., Liu, Q., Ma, J., & Dong, Y. (2013) · Inorganic Chemistry · doi:10.1021/ic302716n · Cited by 79
Tedeschi, C., Azéma, J., Gornitzka, H., Tisnès, P., & Picard, C. (2003) · Dalton Transactions · doi:10.1039/b300159h · Cited by 68
Li, H., Shi, W., Xu, N., Zhang, Z., Niu, Z., Han, T., & Cheng, P. (2012) · Crystal Growth & Design · doi:10.1021/cg300196w · Cited by 62
Self-citationXu, G., Zhao, Y.-H., Shao, K., et al. (2009) · CrystEngComm · doi:10.1039/b904000e · Cited by 57
Canard, G., Koeller, S., Bernardinelli, G., & Piguet, C. (2007) · Journal of the American Chemical Society · doi:10.1021/ja0772290 · Cited by 54
In search for tuneable intramolecular intermetallic interactions in polynuclear lanthanide complexes
Favera, N. D., Guénée, L., Bernardinelli, G., & Piguet, C. (2009) · Dalton Transactions · doi:10.1039/b905131g · Cited by 33
Zaïm, A., Favera, N. D., Guénée, L., Nozary, H., Hoang, T. N. Y., Eliseeva, S. V., Pètoud, S., & Piguet, C. (2013) · Chemical Science · doi:10.1039/c2sc21982d · Cited by 32
Cited by
Metal–Organic Frameworks for Food Safety
Wang, P.-L., Xie, L.-H., Joseph, E. A., Li, J.-R., Su, X.-O., & Zhou, H.-C. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.9b00257 · Cited by 533
Wu, S., Lin, Y., Liu, J., Shi, W., Yang, G., & Cheng, P. (2018) · Advanced Functional Materials · doi:10.1002/adfm.201707169 · Cited by 528
Self-citationLuminescent rare-earth-based MOFs as optical sensors
Mahata, P., Mondal, S. K., Singha, D. K., & Majee, P. (2017) · Dalton Transactions · doi:10.1039/c6dt03419e · Cited by 292
Structural diversity of alkaline-earth 2,5-thiophenedicarboxylates
Balendra, & Ramanan, A. (2017) · Journal of Molecular Structure · doi:10.1016/j.molstruc.2016.11.029 · Cited by 16
Metadata
- Authors
- Zhou, J.-M., Shi, W., Xu, N., & Cheng, P.
- Venue
- Inorganic Chemistry
- Publisher
- American Chemical Society (ACS)
- Published
- 2013-07-02
- Volume
- 52
- Issue
- 14
- Pages
- 8082-8090
- ISSN
- 0020-1669 (ISSN-L)
- 1520-510X
- OpenAlex
- W2316917002
- Cited by
- 319
- References
- 45
- FWCI
- 19.01
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
