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Growing Crystalline Zinc-1,3,5-benzenetricarboxylate Metal–Organic Frameworks in Different Surfactants
Abstract
Six new zinc-1,3,5-benzenetricarboxylate-based metal-organic frameworks (MOFs) have been successfully synthesized using three different surfactants (PEG 400, octanoic acid, and hexadecyltributylphosphonium bromide) as reaction media. These surfactants with different characteristics, such as being neutral, acidic, and cationic, have been demonstrated to show strong effects on directing the crystals' growth and resulted in different secondary building units (SBUs) including an unusual SBU unit [Zn4(μ4-O)(CO2)7]. Our results clearly indicated that the surfactant-thermal method could offer exciting opportunities for preparing novel MOFs or other inorganic crystalline materials with diverse structures and interesting properties.
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Cites
Colloidal nanocrystal synthesis and the organic–inorganic interface
Yin, Y., & Alivisatos, A. P. (2005) · Nature · doi:10.1038/nature04165 · Cited by 3,273
Cited by
He, Y., Hwang, S., Cullen, D. A., Uddin, M. A., Langhorst, L., Li, B., Karakalos, S., Kropf, A. J., Wegener, E. C., Sokolowski, J., et al. (2019) · Energy & Environmental Science · doi:10.1039/c8ee02694g · Cited by 868
Surfactants as promising media in the field of metal-organic frameworks
Zhao, J., Liu, X., Wu, Y., Li, D.-S., & Zhang, Q. (2019) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2019.04.002 · Cited by 386
Self-citationShen, L., Liang, R., Luo, M., Jing, F., & Wu, L. (2015) · Physical Chemistry Chemical Physics · doi:10.1039/c4cp04162c · Cited by 300
Yan, Y., Li, C., Wu, Y., Gao, J., & Zhang, Q. (2020) · Journal of Materials Chemistry A · doi:10.1039/d0ta03749d · Cited by 260
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Metadata
- Authors
- Gao, J., Ye, K., Yang, L., Xiong, W.-W., Ye, L., Wang, Y., & Zhang, Q.
- Venue
- Inorganic Chemistry
- Publisher
- American Chemical Society (ACS)
- Published
- 2013-12-27
- Volume
- 53
- Issue
- 2
- Pages
- 691-693
- ISSN
- 0020-1669 (ISSN-L)
- 1520-510X
- OpenAlex
- W2334758437
- Cited by
- 165
- References
- 1
- FWCI
- 12.10
- Type
- journal article
- Language
- en
- Open access
- closed
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- Gao, J., Ye, K., Yang, L., Xiong, W.-W., Ye, L., Wang, Y., & Zhang, Q. (2014). Growing Crystalline Zinc-1,3,5-benzenetricarboxylate Metal–Organic Frameworks in Different Surfactants. Inorganic Chemistry. https://doi.org/10.1021/ic402692p
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