The DOI matches its Crossref record; 28 of the 28 references it cites were found in a registry or an index.
Ag/ZnO Heterostructure Nanocrystals: Synthesis, Characterization, and Photocatalysis
Abstract
A high yield of the dimer-type heterostructure of Ag/ZnO nanocrystals with different Ag contents is successfully prepared through a simple solvothermal method in the absence of surfactants. The samples are characterized by X-ray diffraction, transmission electron microscopy, X-ray photoelectron spectroscopy, UV-vis spectroscopy, and IR spectroscopy. The results show that all samples are composed of metallic Ag and ZnO; Ag nanoparticles locate on the surface of ZnO nanorods; the binding energy of Ag 3d(5/2) for the Ag/ZnO sample with a Ag content of 5.0 atom % shifts remarkably to the lower binding energy compared with the corresponding value of pure metallic Ag because of the interaction between Ag and ZnO nanocrystals; the concentration of oxygen vacancy for the as-synthesized samples varies with the increasing Ag content, and the Ag/ZnO sample with a Ag content of 5.0 atom % has the largest density of oxygen vacancy. In addition, the relationship between their structure and photocatalytic property is investigated in detail. It is found that the photocatalytic property is closely related to its structure, such as heterostructure, oxygen defect, and crystallinity. The presence of metallic Ag nanoparticles and oxygen vacancy on the surface of ZnO nanorods promotes the separation of photogenerated electron-hole pairs and thus enhances the photocatalytic activity.
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Carbone, L., & Cozzoli, P. D. (2010) · Nano Today · doi:10.1016/j.nantod.2010.08.006 · Cited by 691
Jiang, J., Zhang, X., Sun, P., & Zhang, L. (2011) · The Journal of Physical Chemistry C · doi:10.1021/jp205925z · Cited by 580
Enhanced photocatalytic removal of phenol from aqueous solutions using ZnO modified with Ag
Vaiano, V., Matarangolo, M., Murcia, J. J., Rojas, H., Navío, J. A., & Hidalgo, M. C. (2018) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2017.11.075 · Cited by 512
Tuning of metal oxides photocatalytic performance using Ag nanoparticles integration
Karimi-Maleh, H., Kumar, B. G., Rajendran, S., Qin, J., Vadivel, S., Durgalakshmi, D., Gracia, F., Soto-Moscoso, M., Orooji, Y., & Karimi, F. (2020) · Journal of Molecular Liquids · doi:10.1016/j.molliq.2020.113588 · Cited by 429
Liu, X., Chen, N., Han, B., Xiao, X., Chen, G., Djerdj, I., & Wang, Y. (2015) · Nanoscale · doi:10.1039/c5nr03585f · Cited by 349
Synthesis of graphene–ZnO nanorod nanocomposites with improved photoactivity and anti-photocorrosion
Chen, Z., Zhang, N., & Xu, Y.-J. (2013) · CrystEngComm · doi:10.1039/c3ce27021a · Cited by 329
Senapati, S., Srivastava, S. K., & Singh, S. B. (2012) · Nanoscale · doi:10.1039/c2nr31831h · Cited by 82
Metadata
- Authors
- Zheng, Y., Zheng, L., Zhan, Y., Lin, X., Zheng, Q., & Wei, K.
- Venue
- Inorganic Chemistry
- Publisher
- American Chemical Society (ACS)
- Published
- 2007-07-21
- Volume
- 46
- Issue
- 17
- Pages
- 6980-6986
- ISSN
- 0020-1669 (ISSN-L)
- 1520-510X
- OpenAlex
- W2002674528
- Cited by
- 913
- References
- 28
- FWCI
- 12.07
- Type
- journal article
- Language
- en
- Open access
- closed
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