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Ag/ZnO Heterostructure Nanocrystals: Synthesis, Characterization, and Photocatalysis

Zheng, Yuanhui, Zheng, Lirong, Zhan, Yingying, Lin, Xingyi, Zheng, Qi, Wei, Kemei·2007·Inorganic Chemistry

Abstract

A high yield of the dimer-type heterostructure of Ag/ZnO nanocrystals with different Ag contents is successfully prepared through a simple solvothermal method in the absence of surfactants. The samples are characterized by X-ray diffraction, transmission electron microscopy, X-ray photoelectron spectroscopy, UV-vis spectroscopy, and IR spectroscopy. The results show that all samples are composed of metallic Ag and ZnO; Ag nanoparticles locate on the surface of ZnO nanorods; the binding energy of Ag 3d(5/2) for the Ag/ZnO sample with a Ag content of 5.0 atom % shifts remarkably to the lower binding energy compared with the corresponding value of pure metallic Ag because of the interaction between Ag and ZnO nanocrystals; the concentration of oxygen vacancy for the as-synthesized samples varies with the increasing Ag content, and the Ag/ZnO sample with a Ag content of 5.0 atom % has the largest density of oxygen vacancy. In addition, the relationship between their structure and photocatalytic property is investigated in detail. It is found that the photocatalytic property is closely related to its structure, such as heterostructure, oxygen defect, and crystallinity. The presence of metallic Ag nanoparticles and oxygen vacancy on the surface of ZnO nanorods promotes the separation of photogenerated electron-hole pairs and thus enhances the photocatalytic activity.

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Metadata

Authors
Zheng, Y., Zheng, L., Zhan, Y., Lin, X., Zheng, Q., & Wei, K.
Venue
Inorganic Chemistry
Published
2007-07-21
Volume
46
Issue
17
Pages
6980-6986
ISSN
  • 0020-1669 (ISSN-L)
  • 1520-510X
OpenAlex
W2002674528
Cited by
913
References
28
FWCI
12.07
Type
journal article
Language
en
Open access
closed

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