The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Highly Efficient Colloidal Cobalt- and Rhodium-Catalyzed Hydrolysis of H3N·BH3 in Air
Abstract
The compound H3N.BH3 (1) is currently attracting considerable attention as a potential hydrogen storage material. Group 9 catalysts which rapidly and conveniently hydrolyze aqueous 1 in air are described. When treated with 1 mol % [{Rh(mu-Cl)(1,5-cod)}2] (cod=cyclooctadiene) in air, aqueous 1 undergoes rapid hydrolysis to afford the ionic species [NH4][BO2] in approximately 40 s. Higher catalyst loadings (3 mol %) result in a reduction in reaction time to 10 s. Quantification of the hydrogen evolved revealed that, on average, 2.8 of a maximum possible 3.0 equivalents (93%) were generated during the course of the reaction. Rh(0) species (e.g., Rh black, Rh stabilized on alumina, aqueous Rh colloids) were also found to be active hydrolysis catalysts, and evidence for a heterogeneous mechanism is provided. Significantly, although Ir(0) colloids are less active, aqueous Co(0) colloids are also effective catalysts for this process. This result is particularly important as Co, a first-row metal, is considerably more economical than the precious metal catalysts typically employed.
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Cites
Ni1-xPtx (x = 0−0.12) Hollow Spheres as Catalysts for Hydrogen Generation from Ammonia Borane
Cheng, F., Ma, H., Li, Y., & Chen, J. (2007) · Inorganic Chemistry · doi:10.1021/ic061712e · Cited by 349
Cited by
B–N compounds for chemical hydrogenstorage
Hamilton, C. W., Baker, R. T., Staubitz, A., & Manners, I. (2009) · Chem. Soc. Rev. · doi:10.1039/b800312m · Cited by 1,087
Self-citationHydrogen storage: beyond conventional methods
Dalebrook, A. F., Gan, W., Grasemann, M., Moret, S., & Laurenczy, G. (2013) · Chemical Communications · doi:10.1039/c3cc43836h · Cited by 503
Liquid‐Phase Chemical Hydrogen Storage: Catalytic Hydrogen Generation under Ambient Conditions
Jiang, H., Singh, S. K., Yan, J., Zhang, X., & Xu, Q. (2010) · ChemSusChem · doi:10.1002/cssc.201000023 · Cited by 441
Hou, C.-C., Li, Q., Wang, C.-J., Peng, C.-Y., Chen, Q.-Q., Ye, H.-F., Fu, W.-F., Che, C.-M., López, N., & Chen, Y. (2017) · Energy & Environmental Science · doi:10.1039/c7ee01553d · Cited by 267
Metadata
- Authors
- Clark, T. J., Whittell, G. R., & Manners, I.
- Venue
- Inorganic Chemistry
- Publisher
- American Chemical Society (ACS)
- Published
- 2007-07-31
- Volume
- 46
- Issue
- 18
- Pages
- 7522-7527
- ISSN
- 0020-1669 (ISSN-L)
- 1520-510X
- OpenAlex
- W2043373963
- Cited by
- 210
- References
- 1
- FWCI
- 12.43
- Type
- journal article
- Language
- en
- Open access
- closed
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