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Palladium Nanoparticles Stabilized by an Ionic Polymer and Ionic Liquid: A Versatile System for C−C Cross-Coupling Reactions
Open accessAbstract
Highly stable palladium nanoparticles (Pd NPs), protected by an imidazolium-based ionic polymer (IP) in a functionalized ionic liquid (IL), have been prepared and characterized by transmission electron microscopy (TEM). These Pd NPs are excellent precatalysts for Suzuki, Heck, and Stille coupling reactions and can be stored without undergoing degradation for at least 2 years. The NP-IP-IL system may therefore be considered as an alternative to the traditional palladium on carbon (Pd/C) precatalyst employed in many C-C coupling reactions, also allowing reactions to be conducted under "solvent-free" conditions.
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Cited by
Scheuermann, G. M., Rumi, L., Steurer, P., Bannwarth, W., & Mülhaupt, R. (2009) · Journal of the American Chemical Society · doi:10.1021/ja901105a · Cited by 1,163
Efficient, Selective, and Recyclable Palladium Catalysts in Carbon−Carbon Coupling Reactions
Molnár, Á. (2011) · Chemical Reviews · doi:10.1021/cr100355b · Cited by 1,042
Nanocatalysts for Suzuki cross-coupling reactions
Fihri, A., Bouhrara, M., Nekoueishahraki, B., Basset, J.-M., & Polshettiwar, V. (2011) · Chemical Society Reviews · doi:10.1039/c1cs15079k · Cited by 803
Jin, M., & Lee, D. (2010) · Angewandte Chemie International Edition · doi:10.1002/anie.200905626 · Cited by 323
Metadata
- Authors
- Yang, X., Fei, Z., Zhao, D., Ang, W. H., Li, Y., & Dyson, P. J.
- Venue
- Inorganic Chemistry
- Publisher
- American Chemical Society (ACS)
- Published
- 2008-03-14
- Volume
- 47
- Issue
- 8
- Pages
- 3292-3297
- ISSN
- 0020-1669 (ISSN-L)
- 1520-510X
- OpenAlex
- W1982939536
- Cited by
- 158
- References
- 0
- FWCI
- 9.57
- Type
- journal article
- Language
- en
- Open access
- green
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- Yang, X., Fei, Z., Zhao, D., Ang, W. H., Li, Y., & Dyson, P. J. (2008). Palladium Nanoparticles Stabilized by an Ionic Polymer and Ionic Liquid: A Versatile System for C−C Cross-Coupling Reactions. Inorganic Chemistry. https://doi.org/10.1021/ic702305t
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