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Palladium Nanoparticles Stabilized by an Ionic Polymer and Ionic Liquid: A Versatile System for C−C Cross-Coupling Reactions

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Yang, Xue, Fei, Zhaofu, Zhao, Dongbin, Ang, Wee Han, Li, Yongdan, Dyson, Paul J.·2008·Inorganic Chemistry

Abstract

Highly stable palladium nanoparticles (Pd NPs), protected by an imidazolium-based ionic polymer (IP) in a functionalized ionic liquid (IL), have been prepared and characterized by transmission electron microscopy (TEM). These Pd NPs are excellent precatalysts for Suzuki, Heck, and Stille coupling reactions and can be stored without undergoing degradation for at least 2 years. The NP-IP-IL system may therefore be considered as an alternative to the traditional palladium on carbon (Pd/C) precatalyst employed in many C-C coupling reactions, also allowing reactions to be conducted under "solvent-free" conditions.

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Metadata

Authors
Yang, X., Fei, Z., Zhao, D., Ang, W. H., Li, Y., & Dyson, P. J.
Venue
Inorganic Chemistry
Published
2008-03-14
Volume
47
Issue
8
Pages
3292-3297
ISSN
  • 0020-1669 (ISSN-L)
  • 1520-510X
OpenAlex
W1982939536
Cited by
158
References
0
FWCI
9.57
Type
journal article
Language
en
Open access
green

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CoChat. (2026). Citation check: Palladium Nanoparticles Stabilized by an Ionic Polymer and Ionic Liquid: A Versatile System for C−C Cross-Coupling Reactions. https://app.cochat.ai/papers/10.1021/ic702305t
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Yang, X., Fei, Z., Zhao, D., Ang, W. H., Li, Y., & Dyson, P. J. (2008). Palladium Nanoparticles Stabilized by an Ionic Polymer and Ionic Liquid: A Versatile System for C−C Cross-Coupling Reactions. Inorganic Chemistry. https://doi.org/10.1021/ic702305t

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