The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Iridium-Catalyzed Dehydrogenation of Substituted Amine Boranes: Kinetics, Thermodynamics, and Implications for Hydrogen Storage
Abstract
Dehydrogenation of amine boranes is catalyzed efficiently by the iridium pincer complex (kappa (3)-1,3-(OP ( t )Bu 2) 2C 6H 3)Ir(H) 2 ( 1). With CH 3NH 2BH 3 (MeAB) and with AB/MeAB mixtures (AB = NH 3BH 3), the rapid release of 1 equiv of H 2 is observed to yield soluble oligomeric products at rates similar to those previously reported for the dehydrogenation of AB catalyzed by 1. Delta H for the dehydrogenation of AB, MeAB, and AB/MeAB mixtures has been determined by calorimetry. The experimental heats of reaction are compared to results from computational studies.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Crabtree, G. W., Dresselhaus, M. S., & Buchanan, M. V. (2004) · Physics Today · doi:10.1063/1.1878333 · Cited by 1,610
Cited by
Ammonia–Borane and Amine–Borane Dehydrogenation Mediated by Complex Metal Hydrides
Rossin, A., & Peruzzini, M. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00043 · Cited by 421
Staubitz, A., Sloan, M. E., Robertson, A. P. M., Friedrich, A., Schneider, S., Gates, P. J., Schmedt auf der Günne, J., & Manners, I. (2010) · Journal of the American Chemical Society · doi:10.1021/ja104607y · Cited by 302
Metadata
- Authors
- Dietrich, B. L., Goldberg, K. I., Heinekey, D. M., Autrey, T., & Linehan, J. C.
- Venue
- Inorganic Chemistry
- Publisher
- American Chemical Society (ACS)
- Published
- 2008-09-12
- Volume
- 47
- Issue
- 19
- Pages
- 8583-8585
- ISSN
- 0020-1669 (ISSN-L)
- 1520-510X
- OpenAlex
- W1986735880
- Cited by
- 164
- References
- 1
- FWCI
- 10.44
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
