The DOI matches its Crossref record; 18 of the 18 references it cites were found in a registry or an index.
Mononuclear Lanthanide Single Molecule Magnets Based on the Polyoxometalates [Ln(W5O18)2]9− and [Ln(β2-SiW11O39)2]13−(LnIII = Tb, Dy, Ho, Er, Tm, and Yb)
Abstract
The first two families of polyoxometalate-based single-molecule magnets (SMMs) are reported here. Compounds of the general formula [Ln(W(5)O(18))(2)](9-) (Ln(III) = Tb, Dy, Ho, and Er) and [Ln(SiW(11)O(39))(2)](13-) (Ln(III) = Tb, Dy, Ho, Er, Tm, and Yb) have been magnetically characterized with static and dynamic measurements. Slow relaxation of the magnetization, typically associated with SMM-like behavior, was observed for [Ln(W(5)O(18))(2)](9-) (Ln(III) = Ho and Er) and [Ln(SiW(11)O(39))(2)](13-) (Ln(III) = Dy, Ho, Er, and Yb). Among them, only the [Er(W(5)O(18))(2)](9-) derivative exhibited such a behavior above 2 K with an energy barrier for the reversal of the magnetization of 55 K. For a deep understanding of the appearance of slow relaxation of the magnetization in these types of mononuclear complexes, the ligand-field parameters and the splitting of the J ground-state multiplet of the lanthanide ions have been also estimated.
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Metadata
- Authors
- AlDamen, M. A., Cardona-Serra, S., Clemente-Juan, J. M., Coronado, E., Gaita-Ariño, A., Martí-Gastaldo, C., Luis, F., & Montero, O.
- Venue
- Inorganic Chemistry
- Publisher
- American Chemical Society (ACS)
- Published
- 2009-04-13
- Volume
- 48
- Issue
- 8
- Pages
- 3467-3479
- ISSN
- 0020-1669 (ISSN-L)
- 1520-510X
- OpenAlex
- W1973141298
- Cited by
- 502
- References
- 18
- FWCI
- 17.60
- Type
- journal article
- Language
- en
- Open access
- closed
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