The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
An Acetylacetonate-Based Semiconductor−Sensitizer Linkage
Abstract
Coordination compounds of the general type Ru(dmb) 2 (LL)(PF 6 ) 2, where dmb is 4,4‘-(CH 3 ) 2 -2,2‘-bipyridine and LL is 4-(CH 3 )-4‘-(COOH)-2,2‘-bipyridine, or 4-(CH 3 )-4‘-((CH 2 ) 3 COOH)-2,2‘-bipyridine, or 4-(CH 3 )-4‘-((CH 2 ) 3 COCH 2 COOC 2 H 5 )-2,2‘-bipyridine were prepared for the attachment to semiconductor metal oxide surfaces. The optical and redox properties of these compounds in dichloromethane solution are reported. Binding to porous nanostructured TiO 2 films was analyzed with the Langmuir adsorption isotherm model. Photoelectrochemical measurements of the modified TiO 2 electrodes in regenerative solar cells are reported. The results indicate that intimate electronic coupling between the surface link and the chromophoric ligand is not a strict requirement in the design of sensitizers for photovoltaic applications. Interfacial kinetics for recombination of the electron in the solid with the oxidized form of the sensitizer were quantitated by excited state absorption spectroscopy.
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Cites
A low-cost, high-efficiency solar cell based on dye-sensitized colloidal TiO2 films
O'Regan, B., & Grätzel, M. (1991) · Nature · doi:10.1038/353737a0 · Cited by 28,599
Cited by
Applications of functionalized transition metal complexes in photonic and optoelectronic devices
Kalyanasundaram, K. (1998) · Coordination Chemistry Reviews · doi:10.1016/s0010-8545(98)00189-1 · Cited by 1,515
Abe, R. (2010) · Journal of Photochemistry and Photobiology C: Photochemistry Reviews · doi:10.1016/j.jphotochemrev.2011.02.003 · Cited by 1,223
Electro- and Solar-Driven Fuel Synthesis with First Row Transition Metal Complexes
Dalle, K. E., Warnan, J., Leung, J. J., Reuillard, B., Karmel, I. S., & Reisner, E. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00392 · Cited by 912
Metal complex sensitizers in dye-sensitized solar cells
Polo, A. S., Itokazu, M. K., & Murakami Iha, N. Y. (2004) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2004.04.013 · Cited by 554
Wang, Z.-S., Cui, Y., Dan-oh, Y., Kasada, C., Shinpo, A., & Hara, K. (2007) · The Journal of Physical Chemistry C · doi:10.1021/jp067872t · Cited by 521
Metadata
- Authors
- Heimer, T. A., D'Arcangelis, S. T., Farzad, F., Stipkala, J. M., & Meyer, G. J.
- Venue
- Inorganic Chemistry
- Publisher
- American Chemical Society (ACS)
- Published
- 1996-01-01
- Volume
- 35
- Issue
- 18
- Pages
- 5319-5324
- ISSN
- 0020-1669 (ISSN-L)
- 1520-510X
- OpenAlex
- W1966836042
- Cited by
- 312
- References
- 1
- FWCI
- 17.04
- Type
- journal article
- Language
- en
- Open access
- closed
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